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Selective hydrogenation of unsaturated aldehydes over Pd catalyst supported on N-doped porous carbon

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Abstract

Selective hydrogenation of unsaturated aldehydes is one of the most important reactions in organic chemical industry. Herein, a N-doped Pd catalyst supported on porous carbon (Pd/NC) was prepared and examined on selective hydrogenation of 2-ethyl-2-hexenal (EHEA) to 2-ethylhexanal (EHA). The N-doped Pd/NC catalyst shows a superior catalytic conversion (i.e., about 1.4 times higher than that on the counterpart Pd/C catalyst at 353 K) and a remarkable selectivity (98%) to hydrogenating C=C bond on EHEA to the saturated product (2-ethylhexanal). The catalyst characterization results suggest that N do** can promote the electron density on the surface of Pd, which enhances the adsorption and further activation of hydrogen molecules so that it significantly improves the hydrogenation rate of 2-ethyl-2-hexenal. It is also clarified that the by-product, 2-ethylhexanol is formed via the hydrogenation of C=C bond in 2-ethyl-2-hexenol rather than the C=O group in 2-ethylhexanal. These interesting findings provide a promising strategy for future catalyst design and a meaningful understanding of selective hydrogenation of unsaturated aldehydes on Pd catalyst.

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Acknowledgements

We are grateful for the financial support from the National Natural Science Foundation of China (21878227).

Funding

National Natural Science Foundation of China, 21878227, Yujun Zhao.

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  1. Simin Sun and Deng Pan contribute equally as first author.

Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tian** University, Tian**, 300072, China

    Simin Sun, Deng Pan, Huijiang Huang, Zheng Wang, Yan Xu & Yujun Zhao

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  1. Simin Sun
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  2. Deng Pan
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Correspondence to Yan Xu or Yujun Zhao.

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Sun, S., Pan, D., Huang, H. et al. Selective hydrogenation of unsaturated aldehydes over Pd catalyst supported on N-doped porous carbon. Res Chem Intermed 48, 3129–3142 (2022). https://doi.org/10.1007/s11164-022-04744-3

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