Log in

The influences of GO-SHS hybrids on the mechanical and dielectric properties of EP composites

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Graphene oxide (GO) was prepared by improved Hummer's method and silica hollow sphere (SHS) was fabricated by improved template method. The GO-SHS hybrids were prepared by modified SHS attached to modified GO surface, following which the GO-SHS hybrids were introduced into the epoxy resin (EP) matrix to synthesize GO-SHS/EP composites. The results showed that the mechanical and dielectric properties of GO-SHS/EP composites were enhanced. With the content of 0.3 wt.% GO-3 wt.% SHS, the GO-SHS/EP composites achieved impact and flexural strengths of 23.4 kJ/m2 and 148.4 MPa, respectively, which improved 369% and 72%, respectively, compared with pure EP. At 103 Hz, the dielectric constant of GO-SHS composite is 3.17, which is significantly lower compared to 3.79 for pure EP. This will provide an opportunity to expand the application of epoxy composites in electronic packaging.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Data availability

All data included in this study are available upon request by contact with the corresponding author.

References

  1. J.Y. Lee, J.S. Jang, Polymer 47, 3036 (2006)

    Article  CAS  Google Scholar 

  2. Y. Shen, Y.H. Cong, B.Y. Zhang, Macromol. Mater. Eng. 303, 1 (2018)

    Article  CAS  Google Scholar 

  3. F. Chen, Y.H. Cong, B.Y. Zhang, Liq. Cryst. 43, 1100 (2016)

    Article  CAS  Google Scholar 

  4. J. Chen, A.C. Taylor, J. Mater. Sci. 47, 4546 (2012)

    Article  CAS  Google Scholar 

  5. X.D. Li, Y.Q. **a, W.L. Xu, Polym. Chem. 3, 1629 (2012)

    Article  CAS  Google Scholar 

  6. X. Wang, N. Li, J.Y. Wang, G. Sci, Technol. 155, 11 (2018)

    CAS  Google Scholar 

  7. U.O. Uyor, A.P. Popoola, O. Popoola, Adv. Poly. Tech. 37, 2838 (2018)

    Article  CAS  Google Scholar 

  8. Y.C. Zhou, F. Liu, H. Wang, Polym. Composite. 38, 803 (2015)

    Article  CAS  Google Scholar 

  9. F.L. **, X. Li, J.S. Park, J. Ind. Eng. Chem. 29, 1 (2015)

    Article  CAS  Google Scholar 

  10. L. Ci, J. Bai, Adv. Mater. 16, 2021 (2004)

    Article  CAS  Google Scholar 

  11. M.A. Rafiee, J. Rafiee, Z. Wang, ACS Nano 3(12), 3884 (2009)

    Article  CAS  Google Scholar 

  12. H.J. Salavagione, M.A. Gómez, G. MartÍnez, Macromolecules 42(17), 83 (2009)

    Article  CAS  Google Scholar 

  13. L.J. Romasanta, M. Hernández, M.A. López-Manchado, Res. Lett. 6(1), 508 (2011)

    Google Scholar 

  14. R. Wang, L. Zheng, W. Liu, Compos. Sci. Technol. 87, 29 (2013)

    Article  CAS  Google Scholar 

  15. Y.J. Wan, L.C. Tang, L.X. Gong, Carbon 69, 467 (2014)

    Article  CAS  Google Scholar 

  16. Y. Yang, Y. Chu, Y. Zhang, J. Solid. State. Chem. 179, 470 (2006)

    Article  CAS  Google Scholar 

  17. M. Agrawal, A. Pich, S. Gupta, N.E. Zafeiropoulos, Langmuir 24, 1013 (2008)

    Article  CAS  Google Scholar 

  18. C. Song, G. Gu, Y. Lin, Mater. Res. Bul. 38, 917 (2003)

    Article  CAS  Google Scholar 

  19. D. Wang, C. Song, Y. Lin, Z. Hu, Mater. Lett. 60, 77 (2006)

    Article  CAS  Google Scholar 

  20. Z.U. Rahman, N. Wei, Z. Li, W. Sun, D. Wang, New. J. Chem. 41, 14122 (2017)

    Article  CAS  Google Scholar 

  21. X.M. Zhang, L. Zhang, Q.H. Yang, J. Mater. Chem. A. 2, 7546 (2014)

    Article  CAS  Google Scholar 

  22. T.S. Deng, F. Marlow, Chem. Mater. 24, 536 (2012)

    Article  CAS  Google Scholar 

  23. M. Akhondi, E. Jamalizadeh, Ceram. Int. 47(1), 851 (2021)

    Article  CAS  Google Scholar 

  24. H. Zhou, Z.M. Dang, J.W. Zha, IEEE. 19, 1312 (2012)

    Google Scholar 

  25. S. Wang, L. Gang, J. Pu, BioResources 13(3), 6311 (2018)

    CAS  Google Scholar 

  26. S.Z. Haeri, B. Ramezanzadeh, M. Asghari, J. Colloid. Interf. Sci. 493, 111 (2017)

    Article  CAS  Google Scholar 

  27. Y.L. Chang, J.H. Bae, T.Y. Kim, S.H. Chang, Composites 75, 11 (2015)

    Google Scholar 

  28. Y.L. Chang, Q.V. Le, C. Kim, Chem. Phys. 17, 9369 (2015)

    Google Scholar 

  29. C.M. Gui, H.D. Ma, R.X. Zhang, Langmuir 37(18), 5673 (2021)

    Article  CAS  Google Scholar 

  30. F. Su, C. Lu, S.C. Kuo, W. Zeng, Energ. Fuel. 242, 1441 (2010)

    Article  CAS  Google Scholar 

  31. J.X. Zhao, M.M. Ma, X.H. Yan, Food. Chem. 366, 130616 (2022)

    Article  CAS  Google Scholar 

  32. C.C. Hsu, K.C. Chang, T.C. Huang, Micropor. Mesopor. Mat. 198, 15 (2014)

    Article  CAS  Google Scholar 

  33. K. Liu, S. Lu, S. Li, Iran. Polym. J. 21(8), 497 (2012)

    Article  CAS  Google Scholar 

  34. S.R. Lim, W.S. Chow, Technol. Eng. 50, 182 (2011)

    CAS  Google Scholar 

  35. K. Kumar, M.S. Goyat, A. Solanki, Polym. Composite. 1, 1 (2021)

    Google Scholar 

  36. J.P. Tian, Y. Yang, J.P. Yang, High. Perform. Polym. 33(7), 832 (2021)

    Article  CAS  Google Scholar 

  37. Y.L. Liu, Y.F. Chen, H. Zhao, J Mater Sci: Mater. Electron. 32, 8890 (2021)

    CAS  Google Scholar 

  38. J. Yu, R. Huo, C. Wu, Macromol. Res. 20, 816 (2012)

    Article  CAS  Google Scholar 

  39. Z.M. Dang, L.J. Ma, J.W. Zha, Appl. Phys. 105(4), 1769 (2009)

    Article  CAS  Google Scholar 

  40. Y. Lu, S. Zhang, Z. Geng, New J. Chem. 41(8), 3089 (2017)

    Article  CAS  Google Scholar 

  41. Z. Wang, J.K. Nelson, H. Hillborg, Adv. Mater. 24, 3134 (2012)

    Article  CAS  Google Scholar 

  42. D.R. Dreyer, S. Park, C.W. Bielawski, R.S. Ruoff, Chem. Soc. Rev. 39, 228 (2010)

    Article  CAS  Google Scholar 

  43. T.M. Long, T.M. Swager, J. Am. Chem. Soc. 125, 14113 (2003)

    Article  CAS  Google Scholar 

  44. T. Fukumaru, T. Fujigaya, N. Nakashima, Polym. Chem. 3, 369 (2012)

    Article  CAS  Google Scholar 

  45. H. Zhou, D.Y. Wei, Y. Fan, Mater Sci. Eng. B. 203, 13 (2016)

    Article  CAS  Google Scholar 

  46. L.Z. Guan, L. Weng, Q. Li, Mater. Des. 197, 109241 (2021)

    Article  CAS  Google Scholar 

  47. L. Wan, X. Zhang, G.L. Wu, High. Volt. 2, 167 (2017)

    Article  Google Scholar 

Download references

Funding

The authors have not disclosed any funding.

Author information

Authors and Affiliations

Authors

Contributions

All authors contributed to the study conception and design. Conceptualization, investigation, methodology, material preparation, supervision, data collection and analysis and visualization were performed by HZ, HZ, JG, GL, XT, and LJ. The first draft of the manuscript was written by HZ and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Hong Zhou.

Ethics declarations

Conflict of interest

The authors declare that there is no conflict of interests regarding the publication of this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, H., Zhou, H., Ge, J. et al. The influences of GO-SHS hybrids on the mechanical and dielectric properties of EP composites. J Mater Sci: Mater Electron 33, 21985–21994 (2022). https://doi.org/10.1007/s10854-022-08987-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-022-08987-z

Navigation