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Influence of alloying titanium carbonitride by transition metals of groups IV–VI on the interaction with the nickel melt

  • Refractory, Ceramic, and Composite Materials
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Russian Journal of Non-Ferrous Metals Aims and scope Submit manuscript

Abstract

The influence of alloying titanium carbonitride TiC0.5N0.5 by transition metals of Groups IV–VI on the mechanism of contact interaction with the nickel melt is studied. It is established that alloying metals exert a strongly destabilizing influence on titanium carbonitride TiC0.5N0.5, simultaneously increasing both its dissolution rate in nickel and the degree of process incongruence (the preferential transition of alloying metal and carbon into the melt). The influence of alloying on the phase stability of titanium carbonitride TiC0.5N0.5 in contact with a nickel melt manifests itself in its dehomogenization or phase separation. The destabilizing effect of alloying additives enhances in a series MeIV–MeV–MeVI parallel with a decrease in their nitrogen affinity.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620219, Russia

    V. A. Zhilyaev

  2. Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620990, Russia

    E. I. Patrakov

Authors
  1. V. A. Zhilyaev
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  2. E. I. Patrakov
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Corresponding author

Correspondence to V. A. Zhilyaev.

Additional information

Original Russian Text © V.A. Zhilyaev, E.I. Patrakov, 2014, published in Izvestiya Vysshikh Uchebnykh Zavedenii. Poroshkovaya Metallurgiya i Funktsional’nye Pokrytiya, 2014, No. 4, pp. 30–36.

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Zhilyaev, V.A., Patrakov, E.I. Influence of alloying titanium carbonitride by transition metals of groups IV–VI on the interaction with the nickel melt. Russ. J. Non-ferrous Metals 57, 141–147 (2016). https://doi.org/10.3103/S1067821216020140

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  • DOI: https://doi.org/10.3103/S1067821216020140

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