Abstract
Specific features and regularities of reactions of titanium carbide alloyed over the sublattice of nonmetals (N, O) with the nickel melt are analyzed. It is established that the partial substitution of carbon in TiC by nitrogen decreases its dissolution rate in nickel and increases the degree of process incongruence (the transfer of carbon into the melt is preferential compared with titanium). The concentration dependence of the dissolution rate of TiC x N z in nickel changes its sign to the opposite one compared with approaching the system to equilibrium. Titanium carbonitride is not recrystallized through the nickel solution as the only phase, and mainly its carbide component is subjected to recrystallization. It is revealed that the partial substitution of carbon in TiC to oxygen increases its dissolution rate in nickel. The dissolution of oxycarbide TiC0.6O0.4 in nickel is accompanied by the gradual loss of its carbon until titanium monoxide is formed and by its further disproportionation. The peculiarity of the interaction mechanism of titanium oxycarbides with the nickel melt is determined by reaction [C] + [O] = CO↑ in the liquid phase.
Similar content being viewed by others
References
Kiparisov, S.S., Levinskii, Yu.V., and Petrov, A.P., Karbid titana: Poluchenie, svoistva, primenenie (Titanium carbide: Preparatioin, Properties, Application), Moscow: Metallurgiya, 1987.
Lengauer, W. and Eder, A., Carbides: Transition Metal Solid-State Chemistry. Encyclopedia of Inorganic Chemistry, Chichester: Willey, 2005.
Durlu, N., J. Eur. Ceram. Soc., 1999, vol. 19, p. 2415.
Bellosi, A., Calzavarini, R., Faga, M.G., et al., J. Mater. Proc. Technol., 2003, vols. 143–144, p. 527.
Chun, D.I., Kim, D.Y., and Eun, K.Y., J. Am. Ceram. Soc., 1993, vol. 76, no. 8, p. 2049.
Yanaba, Y., Takahashi, T., and Hayashi, K.A., J. Jap. Soc. Powder & Powder Metall., 2004, vol. 51, no. 5, p. 374.
Zhilyaev, V.A. and Patrakov, E.I., Izv. Vyssh. Uchebn. Zaved., Poroshk. Metall. Funkts. Pokryt., 2014, no. 1, p. 39.
Zhang, S., Key Eng. Mater., 1998, vols. 138–140, p. 521.
Zhou, S., Zhao, W., and **ong, W., Int. J. Refract. Meter. Hard Mater., 2009, vol. 27, p. 26.
Krushinskii, A.N., Turtsevich, I.V., Androsov, V.N., and Prokop’ev, V.P., in Fiziko-mekhanicheskie i ekspluatatsionnye svoistva instrumental’nykh i konstruktsionnykh materialov (Physicomechanical and Operational Properties of Construction Materials), Krasnoyarsk: Krasnoyarsk Politekh. Inst., 1976, issue 5, p. 51.
Fromm, E. and Gebhard, E., Gazy i uglerod v metallakh (Gases and Carbon in Metals) Linchevskii, B.V., Ed., Moscow: Metallurgiya, 1980.
Zhilyaev, V.A., Izv. Vyssh. Uchebn. Zaved., Poroshk. Metall. Funkts. Pokryt., 2014, no. 2, p. 31.
Zhilyaev, V.A., Materialovedenie, 2012, no. 3, p. 3.
Metallokhimicheskie svoistva elementov Periodicheskoi sistemy: Spravochnik (Metallochemical Properties of Elements of the Periodic Table: Handbook), Kornilov, I.I., Ed., Moscow: Nauka, 1966.
Kowanda, C. and Speidel, M.O., Scr. Mater., 2003, vol. 48, p. 1073.
Niki, E. and Masato, K., J. Jap. Inst. Met., 1970, vol. 34, no. 9, p. 879.
Patrakov, E.I., Contact Interaction of Alloyed Titanium Carbide with Nickel-Based Melts, Cand. Sci. (Chem.) Dissertation, Yekaterinburg: Inst. Khim. Tverd. Tela, Ural. Otd. Ross. Akad. Nauk, 2009.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Original Russian Text © V.A. Zhilyaev, E.I. Patrakov, 2014, published in Izvestiya Vysshikh Uchebnykh Zavedenii. Poroshkovaya Metallurgiya i Funktsional’nye Pokrytiya, 2014, No. 3, pp. 49–54.
About this article
Cite this article
Zhilyaev, V.A., Patrakov, E.I. Regularities of reactions of titanium carbonitrides and oxycarbides with nickel. Russ. J. Non-ferrous Metals 57, 69–74 (2016). https://doi.org/10.3103/S1067821216010144
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1067821216010144