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Complex Precipitation Sequences of Al-Cu-Li-(Mg) Alloys Characterized in Relation to Thermal Ageing Processes

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

The Al-Cu-Li-(Mg) alloy is a high-performance lightweight material strengthened by complex coexisting precipitates that form in the alloy upon thermal ageing. Using high-resolution (scanning) transmission electron microscopy in association with first-principles energy calculations, we systematically studied the complex coexisting precipitates in the alloys and correlated their precipitation sequences with thermal ageing processes applied. The principal results are the following: (1) eight types of precipitates can be observed in the alloy; (2) of these precipitates, the T 1-phase is most stable. The S-phase precipitates with segregated Li atoms at their interfacial edges are unexpectedly more stable than the σ-phase; (3) the T 1-phase has a characteristic precursor that plays the key role in its nucleation and growth.

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References

  1. T. Dursun, C. Soutis, Mater. Design 56, 862 (2014)

    Article  Google Scholar 

  2. E.A. Starke Jr, J.T. Staley, Prog. Aerosp. Sci. 32, 131 (1996)

    Article  Google Scholar 

  3. F.W. Gayle, F.H. Heubaum, J.R. Pickens, Scr. Metall. Mater. 24, 79 (1990)

    Article  Google Scholar 

  4. A.K. Shukla, W.A. Baeslack III, Scr. Mater. 56, 513 (2007)

    Article  Google Scholar 

  5. A. Gaber, N. Afify, Phys. B Condens. Matter. 315, 1 (2002)

    Article  Google Scholar 

  6. B.P. Huang, Z.Q. Zheng, Acta Mater. 46, 4381 (1998)

    Article  Google Scholar 

  7. H.Y. Li, Y. Tang, Z.D. Zeng, Z.Q. Zheng, F. Zheng, Mater. Sci. Eng. A 498, 314 (2008)

    Article  Google Scholar 

  8. X.X. Yu, Y.R. Zhang, D.F. Yin, Z.M. Yu, S.F. Li, Acta Metall. Sin. (Engl. lett.) 28, 817 (2015)

    Article  Google Scholar 

  9. C.E. Cross, in aluminum–lithium alloys II, ed. by T.H. Sanders Jr., E.A. Starke Jr, Proceedings of the 2nd International Aluminum–Lithium Conference, California, April 1983 (TMS-AIME, Warrendale, 1984), p. 675

  10. A. Guinier, Nature 142, 569 (1938)

    Article  Google Scholar 

  11. G.D. Preston, Nature 142, 570 (1938)

    Article  Google Scholar 

  12. T.J. Konno, K. Hiraga, M. Kawasaki, Scr. Mater. 44, 2303 (2001)

    Article  Google Scholar 

  13. J. Silcock, T. Heal, H. Hardy, J. Inst. Met. 82, 239 (1954)

    Google Scholar 

  14. S.M. Kumaran, N. Priyadharsini, V. Rajendran, T. Jayakumar, P. Palanichamy, P. Shankar, B. Raj, Mater. Sci. Eng. A 435–436, 29 (2006)

    Article  Google Scholar 

  15. J.M. Silcock, J. Inst. Met. 88, 357 (1959–60)

  16. B. Decreus, A. Deschamps, F. De Geuser, P. Donnadieu, C. Sigli, M. Weyland, Acta Mater. 61, 2207 (2013)

    Article  Google Scholar 

  17. R. Yoshimura, T.J. Konno, E. Abe, K. Hiraga, Acta Mater. 51, 2891 (2003)

    Article  Google Scholar 

  18. R.D. Schueller, A.K. Sachdev, F.E. Wawner, Scr. Metall. Mater. 27, 1289 (1992)

    Article  Google Scholar 

  19. Z.R. Pan, Z.Q. Zheng, Z.Q. Liao, S.C. Li, Mater. Lett. 64, 942 (2010)

    Article  Google Scholar 

  20. H.K. Hardy, J.M. Silock, J. Inst. Met. 84, 423 (1955–1956)

  21. S. Van Smaalen, A. Meetsma, J.L. De Boer, P.M. Bronsveld, J. Solid State Chem. 85, 293 (1990)

    Article  Google Scholar 

  22. C. Dwyer, M. Weyland, L.Y. Chang, B.C. Muddle, Appl. Phys. Lett. 98, 201901–201909 (2011)

    Article  Google Scholar 

  23. P. Donnadieu, Y. Shao, F. De Geuser, G.A. Botton, S. Lazar, M. Cheynet, M. de Boissieu, A. Deschamps, Acta Mater. 59, 462 (2011)

    Article  Google Scholar 

  24. H. Suzuki, M. Kanno, N. Hayashi, J. Jpn. Inst. Light. Met. 32, 88 (1982)

    Google Scholar 

  25. J.C. Huang, A.J. Ardell, Mater. Sci. Technol. 3, 176 (1987)

    Google Scholar 

  26. B. Noble, G.E. Thompson, Metal. Sci. J. 6, 167 (1972)

    Article  Google Scholar 

  27. K.S. Kumar, S.A. Brown, J.R. Pickens, Acta Mater. 44, 1899 (1996)

    Article  Google Scholar 

  28. M.J. Yin, J.H. Chen, S.B. Wang, Z.R. Liu, L.M. Cha, S.Y. Duan, C.L. Wu, Trans. Nonferr. Met. Soc. China 26, 1 (2016)

    Google Scholar 

  29. B. Decreus, A. Deschamps, F. de Geuser, C. Sigli, Adv. Eng. Mater. 15, 1082 (2013)

    Article  Google Scholar 

  30. P.D. Nellist, S.J. Pennycook, Ultramicroscopy 78, 111 (1999)

    Article  Google Scholar 

  31. S. Hillyard, J. Silcox, Ultramicroscopy 58, 6 (1995)

    Article  Google Scholar 

  32. G. Kresse, J. Furthmüller, Phys. Rev. B 54, 11169 (1996)

    Article  Google Scholar 

  33. J.P. Perdew, J. Chevary, S. Vosko, K.A. Jackson, M.R. Pederson, D. Singh, C. Fiolhais, Phys. Rev. B 46, 6671 (1992)

    Article  Google Scholar 

  34. J.P. Perdew, Y. Wang, Phys. Rev. B 45, 13244 (1992)

    Article  Google Scholar 

  35. H.J. Monkhorst, J.D. Pack, Phys. Rev. B 13, 5188 (1976)

    Article  Google Scholar 

  36. Z.R. Liu, J.H. Chen, S.B. Wang, D.W. Yuan, M.J. Yin, C.L. Wu, Acta Mater. 59, 7396 (2011)

    Article  Google Scholar 

  37. S.B. Wang, J.H. Chen, M.J. Yin, Z.R. Liu, D.W. Yuan, J.Z. Liu, C.H. Liu, C.L. Wu, Acta Mater. 60, 6573 (2012)

    Article  Google Scholar 

  38. Z. Gao, J.Z. Liu, J.H. Chen, S.Y. Duan, Z.R. Liu, W.Q. Ming, C.L. Wu, J. Alloys Compd. 624, 22 (2015)

    Article  Google Scholar 

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 51371081, 11427806, 51471067, 51501059 and 51171063) and the National Basic Research Program of China (No. 2009CB623704). The authors are grateful to Dr. Z.J. Shen, Prof. J.X. Li and Prof. Z. Zhang for great helps in using their HRTEM facility at Zhejiang University.

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Correspondence to Jiang-Hua Chen.

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Gao, Z., Chen, JH., Duan, SY. et al. Complex Precipitation Sequences of Al-Cu-Li-(Mg) Alloys Characterized in Relation to Thermal Ageing Processes. Acta Metall. Sin. (Engl. Lett.) 29, 94–103 (2016). https://doi.org/10.1007/s40195-016-0366-5

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  • DOI: https://doi.org/10.1007/s40195-016-0366-5

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