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Phase Transition, Large Strain and Energy Storage in Ferroelectric (Bi0.5Na0.5)TiO3-BaTiO3 Ceramics Tailored by (Mg1/3Nb2/3)4+ Complex Ions

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Abstract

Lead-free relaxor-ferroelectric (Mg1/3Nb2/3)4+ complex ions modified (Bi0.5Na0.5)0.94Ba0.06TiO3 (BNBT-xMN) ceramics were fabricated by traditional solid-phase reaction sintering, and the effects of (Mg1/3Nb2/3)4+ complex ions on the structural, ferroelectric, dielectric, energy storage, and strain properties of these ceramics were studied. All of the samples illustrated a single perovskite phase with a pseudo-cubic structure. Electric field-induced polarization and strain hysteresis loops indicated the occurrence of reversible ferroelectric-to-relaxor phase transition, which gave rise to a large strain of 0.49%. (Mg1/3Nb2/3)4+ complex ions greatly influenced the coercive field and remanent polarization of the ceramics; these properties also affected energy storage density of the materials. The optimal energy storage density and efficiency of the ceramics were 0.54 J/cm3 and 38.4%, respectively, when x = 0.04. These results may stem from the electric field-induced transition between the ferroelectric and relaxor-ferroelectric phase of the proposed ceramics.

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Acknowledgments

This work is supported by the National Nature Science Foundation of China (11664006, 61741105), Guangxi Nature Science Foundation (2016GXNSFAA380069) and Guangxi Key Laboratory of Information Materials (161001-Z, 171009-Z).

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Authors and Affiliations

  1. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Yabin Sun, Yangyang Zhao, Jiwen Xu, Ling Yang, Changrong Zhou, Guanghui Rao & Hua Wang

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  1. Yabin Sun
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  2. Yangyang Zhao
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  3. Jiwen Xu
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Correspondence to Jiwen Xu or Ling Yang.

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Sun, Y., Zhao, Y., Xu, J. et al. Phase Transition, Large Strain and Energy Storage in Ferroelectric (Bi0.5Na0.5)TiO3-BaTiO3 Ceramics Tailored by (Mg1/3Nb2/3)4+ Complex Ions. J. Electron. Mater. 49, 1131–1141 (2020). https://doi.org/10.1007/s11664-019-07770-x

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