Abstract
The present study is aimed at the development of scientific and technological approaches to the production and exploitation of adsorption systems for natural gas storage at low temperatures. In this work, a monolithic microporous carbon adsorbent is proposed for the accumulation of natural gas; the comprehensive investigations of its structure and properties were carried out. The proposed adsorbent was used for filling up a mobile adsorption natural gas storage reservoir (an adsorber) equipped with the internal and external heat exchangers which provided different modes of fueling/delivery process. The adsorber endured the integrated reliability testing under isothermal, adiabatic and low-temperature conditions of gas fueling/delivery modes. The adsorption characteristics were determined at the pressures up to 10 MPa and within the temperature range from 238 to 293 K; the energy consumptions upon the processes of gas fueling and adsorber cooling were accessed depending on the fueling mode; the temperature variations occurring in the adsorber upon the gas fueling/delivery processes were studied within the pressure range from 0.05 to 10 MPa. Cyclic testings of the mobile adsorber of natural gas were performed to determine an influence of the cyclic loading on the adsorption capacity of the adsorbent.
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Notes
According to NIST, the normal conditions for gas volume determination (NTP) are T=293.15 K, P=101,325 Pa.
Abbreviations
- a :
-
Absolute adsorption, mmol/g
- E :
-
Characteristic energy of adsorption for gas, J/mol
- E 0 :
-
Characteristic adsorption energy of standard benzene vapor, kJ/mol
- M :
-
Mass of adsorbed methane, g
- P :
-
Pressure, MPa
- S BET :
-
Specific surface area, or BET surface area, m2/g
- T :
-
Temperature, K
- t :
-
Time of methane adsorption/desorption, s
- τ :
-
Time of fueling/delivery of the adsorber, h
- q st :
-
Differential molar isosteric heat of adsorption, kJ/mol
- 2θ:
-
Angle between a reflected X-ray beam and the incident X-ray beam, degrees
- V a :
-
Specific volume of accumulated methane, m3/m3
- W 0 :
-
Micropore volume, cm3/g
- X 0 :
-
Average effective half-width of micropores, nm
- a:
-
Adsorbed
- st:
-
Isosteric
- ANG:
-
Adsorbed natural gas
- CNG:
-
Compressed natural gas
- LNG:
-
Liquefied natural gas
- MANG:
-
Mobile adsorber of natural gas
- NLDFT:
-
Non localized density functional theory
- NTP:
-
Normal temperature (293.15 K) and atmosphere pressure (101,325 Pa)
- SEM:
-
Scanning Electron Microscopy
- XRD:
-
X-ray diffraction
References
Agarwal, R.K., Schwarz, J.A.: Analysis of high-pressure adsorption of gases on activated carbon by potential-theory. Carbon 26, 873–887 (1988)
Alhasan, S., Carriveau, R., Ting, D.S.-K.: A review of adsorbed natural gas storage technologies. Int. J. Environ. Stud. 73(3), 343–356 (2016). https://doi.org/10.1080/00207233.2016.1165476
Arnold, L., Averlant, G., Marx, S., Weickert, M.: Metal-organic frameworks for natural gas storage in vehicles. Chem.Ing. Technik. 85, 1726–1733 (2013)
Barrer, R.M., Papadopoulos, R.: The sorption of krypton and xenon in zeolites at high pressures and temperatures. I. Chabazite. Proc. R. Soc. A. 326(1566), 315–330 (1972). https://doi.org/10.1098/rspa.1972.0011
Bastos-Neto, M., Torres, A.E.B., Azevedo, D.C.S., Cavalcante Jr., C.L.: A theoretical and experimental study of charge and discharge cycles in a storage vessel for adsorbed natural gas. Adsorption. 11, 147–157 (2005). https://doi.org/10.1007/s10450-005-4906-y
Bastos-Neto, M., Canabrava, D.V., Torres, A.E.B., Rodriguez-Castellón, E., Jiménez-López, A., Azevedo, D.C.S., Cavalcante Jr., C.L.: Effects of textural and surface characteristics of microporous activated carbons on the methane adsorption capacity at high pressures. Appl. Surf. Sci. 253, 5721–5725 (2007). https://doi.org/10.1016/j.apsusc.2006.12.056
Bazan, R.E., Bastos-Neto, M., Staudt, R., Papp, H., Azevedo, D.C.S., Cavalcante Jr., C.L.: Adsorption equilibria of natural gas components on activated carbon: pure and mixed gas isotherms. Adsorpt. Sci. Technol. 26, 323–332 (2008). https://doi.org/10.1260/026361708787548783
Brunauer, S.: The adsorption of gases and vapors, vol. I. Oxford University Press, Oxford (1943)
Bilóe, S., Goetz, V., Mauran, S.: Dynamic discharge and performance of a new adsorbent for natural gas storage. AIChE J. 47(12), 2819–2830 (2001)
Bilóe, S., Goetz, V., Guillot, A.: Optimal design of an activated carbon for an adsorbed natural gas storage system. Carbon 40(8), 1295–1308 (2002)
Chang, K.J., Talu, O.: Behavior and performance of adsorptive natural gas storage cylinders during discharge. Appl. Therm. Eng. 16(5), 359–374 (1996). https://doi.org/10.1016/1359-4311(95)00017-8
Chkhaidze, E.V., Fomkin, A.A., Serpinskii, V.V., Tsitsishvili, G.V.: Adsorption of methane on NaX zeolite in the subcritical and supercritical regions. Russ. Chem. Bull. 34(5), 886–890 (1985). https://doi.org/10.1007/BF01142768
DeSantis, D., Mason, J.A., James, B.D., Houchins, C., Long, J.R., Veenstra, M.: Techno-economic analysis of metal-organic frameworks for hydrogen and natural gas storage. Energ. Fuel. 31, 2024–2032 (2017). https://doi.org/10.1021/acs.energyfuels.6b02510
Dubinin, M.M.: Physical adsorption of gases and vapors in micropores. In: Cadenhead, D.D. (ed.) Progress in Surface and Membrane Science, pp. 1–69. Academic Press, London (1975)
Feroldi, M., Neves, A.C., Borba, C.E., Alves, H.J.: Methane storage in activated carbon at low pressure under different temperatures and flow rates of charge. J. Clean. Prod. 172, 921–926 (2018). https://doi.org/10.1016/j.jclepro.2017.10.247
Fomkin, A.A., Shkolin, A.V., Menshchikov, I.E., Pulin, A.L., Pribylov, A.A., Smirnov, I.A.: Measurement of adsorption of methane at high pressures for alternative energy systems. Meas. Tech. 58(12), 1387–1391 (2016). https://doi.org/10.1007/s11018-016-0904-6
Fomkin, A.A., Shkolin, A.V., Menshchikov, I.E., Tsivadze, A.Y.: Storage method of natural gas by adsorption in industrial gas cylinders. Patent RU 2616140. Effective date for property rights: 24.12.2015. Date of publication: 12.04.2017 Bull. No 11
Fomkin, A.A., Shkolin, A.V., Menshchikov, I.E., Tsivadze, A.Y.: Method of storing the natural gas in the adsorbed form at the reduced temperatures. RU patent 2650012 Effective date for property rights: 27.12.2016. Date of publication: 06.04.2018 Bull. No 10
Fomkin, A.A., Shkolin, A.V., Pulin, A.L., Men’shchikov, I.E., Khozina, E.V.: Adsorption-induced deformation of adsorbents. Colloid J. 80(5), 578–586 (2018). https://doi.org/10.1134/S1061933X18050083
Golovoy, A., Braslaw, J.: On-board storage and home refueling options for natural gas vehicles, SAE Technical Paper 830382. 1983. https://doi.org/10.4271/830382
Gregg, S.J., Sing, K.S.W.: Adsorption, Surface Area and Porosity, 2nd edn. Academic Press Inc., San Diego (1982)
Kerr, R.A.: Natural gas from shale bursts onto the scene. Science 328, 1624–1626 (2010). https://doi.org/10.1126/science.328.5986.1624
Khorashadizadeh, M., Shahrak, M.N., Shahsavand, A.: Reliable modeling of discharge process for adsorbed natural gas storage tanks. Korean J. Chem. Eng. 31(11), 1994–2002 (2014). https://doi.org/10.1007/s11814-014-0100-9
Mennon, V.C., Komarneni, S.: Porous adsorbents for vehicular natural gas storage: a review. J. Porous Mater. 5, 43–58 (1998)
Men´shchikov, I.E., Fomkin, A.A., Shkolin, A.V., Yakovlev, VYu., Khozina, E.V.: Optimization of structural and energy characteristics of adsorbents for methane storage. Russ. Chem. Bull. 67, 1814–1822 (2018)
Lozano-Castelló, D., Cazorla-Amorós, D., Linares-Solano, A., Quinn, D.F.: Micropore size distributions of activated carbons and carbon molecular sieves assessed by high-pressure methane and carbon dioxide adsorption isotherms. J. Phys. Chem. B 106, 9372–9379 (2002a)
Lozano-Castelló, D., Cazorla-Amorós, D., Linares-Solano, A., Quinn, D.F.: Influence of pore size distribution on methane storage at relatively low pressure: preparation of activated carbon with optimum pore size. Carbon 40, 989–1002 (2002b). https://doi.org/10.1016/S0008-6223(01)00235-4
Makal, T.A., Li, J.R., Lu, W., Zhou, H.C.: Methane storage in advanced porous materials. Chem. Soc. Rev. 41, 7761–7779 (2012). https://doi.org/10.1039/c2cs35251f
Mason, J.A., Oktawiec, J., Taylor, M.K., Hudson, M.R., Rodriguez, J., Bachman, J.E., Gonzalez, M.I., Cervellino, A., Guagliardi, A., Brown, C.M., Llewellyn, P.L., Masciocchi, N., Long, J.R.: Methane storage in flexible metal–organic frameworks with intrinsic thermal management. Nature 527, 357–371 (2015). https://doi.org/10.1038/nature15732
Men’shchikov, I.E., Shkolin, A.V., Fomkin, A.A.: Adsorption and thermal deformation of microporous carbon adsorbents: measurement and results. Meas. Tech. 60, 1051–1057 (2018). https://doi.org/10.1007/s11018-018-1317-5
Menshchikov, I.E., Fomkin, A.A., Tsivadze, A.Y., Shkolin, A.V., Strizhenov, E.M., Khozina, E.V.: Adsorption accumulation of natural gas based on microporous carbon adsorbents of different origin. Adsorption 23, 327–339 (2017)
Mota, J.P.B., Saatdjian, E., Tondeur, D., Rodrigues, A.E.: A simulation model of a high-capacity methane adsorptive storage system. Adsorption 1(1), 17–27 (1995)
Mota, J., Rodrigues, A., Saatdjian, E., Tondeur, D.: Dynamics of natural gas adsorption storage systems employing activated carbon. Carbon 35(9), 1259–1270 (1997)
Mota, J.: Impact of gas composition on natural gas storage by adsorption. AIChE J. 45(1), 986–996 (1999)
Nie, Z., Lin, Y., **, X.: Research on the theory and application of adsorbed natural Gas used in new energy vehicles: a review. Front. Mech. Eng. 11(3), 258–274 (2016). https://doi.org/10.1007/s11465-016-0381-2
Park, J.E., Lee, G.B., Hwang, S.Y., Kim, J.H., Hong, B.U., Kim, H., Kim, S.: The effects of methane storage capacity using upgraded activated carbon by KOH. Appl. Sci. 8(9), 1596 (2018). https://doi.org/10.3390/app8091596
Patil, K.H., Sahoo, S.: Charge characteristics of adsorbed natural gas storage system based on MAXSORB III. J. Nat. Gas Sci. Eng. 52, 267–282 (2018)
Policicchio, A., Filosa, R., Abate, S., Desiderio, G., Colavita, E.: Activated carbon and metal organic framework as adsorbent for low-pressure methane storage applications: an overview. J. Porous Mater. 24, 905–922 (2017). https://doi.org/10.1007/s10934-016-0330-9
Prajwal, B.P., Ayappa, K.G.: Evaluating methane storage targets: from powder samples to onboard storage systems. Adsorption 20, 769–776 (2014). https://doi.org/10.1007/s10450-014-9620-1
Pribylov, A.A., Serpinskii, V.V., Kalashnikov, S.M.: Adsorption of gases by microporous adsorbents under pressures up to hundreds megapascals. Zeolites 11(8), 846–849 (1991). https://doi.org/10.1016/S0144-2449(05)80067-3
Ravikovitch, P.I., Vishnyakov, A., Russo, R., Neimark, A.V.: Unified approach to pore size characterization of microporous carbonaceous materials from N2, Ar, and CO2 adsorption isotherms. Langmuir 16(5), 2311–2320 (2000)
Ridha, F.N., Yunus, R.M., Rashid, M., Ismail, A.F.: Thermal analysis of adsorptive natural gas storages during dynamic charge phase at room temperature. Exper. Therm. Fluid Sci. 32(1), 14–22 (2007). https://doi.org/10.1016/j.expthermflusci.2007.01.002
Rios, R.B., Bastos-Neto, M., Amora Jr., M.R., Torres, A.E.B., Azevedo, D.C.S., Cavalcante Jr., C.L.: Experimental analysis of the efficiency on charge/discharge cycles in natural gas storage by adsorption. Fuel 90(1), 113–119 (2011). https://doi.org/10.1016/j.fuel.2010.07.039
Saez, A., Toledo, M.: Thermal effect of the adsorption heat on an adsorbed natural gas storage. Appl. Therm. Eng. 29(13), 2617–2623 (2009). https://doi.org/10.1016/j.applthermaleng.2008.10.020
Santos, J., Marcondes, F., Gurgel, J.M.: Performance analysis of a new tank configuration applied to the natural gas storage systems by adsorption. Appl. Therm. Eng. 29(11–12), 2365–2372 (2009). https://doi.org/10.1016/j.applthermaleng.2008.12.001
Shen, D., Bulow, M.: Isosteric study of sorption thermodynamics of single gases and multi-component mixtures on microporous materials. Microporous Mesoporous Mater. 22(1–3), 237–249 (1998). https://doi.org/10.1016/S1387-1811(98)00090-0
Shkolin, A.V., Fomkin, A.A.: Thermodynamics of methane adsorption on the microporous carbon adsorbent ACC. Russ. Chem. Bull. 57(9), 1799–1805 (2008a). https://doi.org/10.1007/s11172-008-0242-1
Shkolin, A.V., Fomkin, A.A., Sinitsyn, V.A.: Methane adsorption on AUK microporous carbon adsorbent. Colloid J. 70(6), 796–801 (2008). https://doi.org/10.1134/s1061933x08060173
Shkolin, A.V., Fomkin, A.A.: Thermodynamics of methane adsorption on the microporous carbon adsorbent ACC. Russ. Chem. Bull. 57(9), 1799–1805 (2008b). https://doi.org/10.1007/s11172-008-0242-1
Shkolin, A.V., Fomkin, A.A.: Deformation of AUK microporous carbon adsorbent induced by methane adsorption. Colloid J. 71(1), 119–124 (2009). https://doi.org/10.1134/S1061933X09010153
Shkolin, A.V., Tsivadze, A.Y., Anuchin, K.M., Men’shchikov, I.E., Pulin, A.L.: Experimental study and numerical modeling: methane adsorption in microporous carbon adsorbent over the subcritical and supercritical temperature regions. Prot. Met. Phys. Chem. Surf. 52(6), 955–963 (2016). https://doi.org/10.1134/S2070205116060186
Shkolin, A.V., Fomkin, A.A.: Measurement of carbon-nanotube adsorption of energy-carrier gases for alternative energy systems. Meas. Tech. 61(4), 395–401 (2018). https://doi.org/10.1007/s11018-018-1440-3
Simon, C.M., Kim, J., Gomez-Gualdron, D.A., Camp, J.S., Chung, Y.G., Martin, R.L., Mercado, R., Deem, M.W., Gunter, D., Haranczyk, M., Sholl, D.S., Snurr, R.Q., Smit, B.: The materials genome in action: identifying the performance limits for methane storage. Energy Environ. Sci. 8, 1190–1199 (2015). https://doi.org/10.1039/c4ee03515a
Solar, C., Blanco, A.G., Vallone, A., Sapag, K.: Adsorption of methane in porous materials as the basis for the storage of natural gas. Nat. Gas 10, 205–244 (2010)
Strizhenov, E.M., Shkolin, A.V., Fomkin, A.A., Sinitsyn, V.A., Zherdev, A.A., Smirnov, I.A., Pulin, A.L.: Low temperature adsorption of methane on microporous AU-1 carbon adsorbent. Prot. Met. Phys. Chem. Surf. 50(1), 15–21 (2014). https://doi.org/10.1134/S2070205114010146
Tabor, D.: The hardness of metals. Oxford University Press Inc., New York (1951)
Talu, O: An overview of adsorptive storage of natural gas. In Suzuki, M. (ed) Proceedings International Conference on Fundamentals of Adsorption, Kyoto, pp. 655-662 (1992)
Vasiliev, L.L., Kanonchik, L.E., Mishkinis, D.A., Rabetsky, M.I.: Int. J. Therm. Sci. 39, 1047–1055 (2000). https://doi.org/10.1016/S1290-0729(00)01178-9
Wegrzyn, J., Gurevich, M.: Adsorbent storage of natural gas. Appl. Energy 55(2), 71–83 (1996)
Wilmer, C.E., Leaf, M., Lee, C.Y., Farha, O.K., Hauser, B.G., Hupp, J.T., Snurr, R.Q.: Large-scale screening of hypothetical metal-organic frameworks. Nat. Chem. 4, 83–89 (2011). https://doi.org/10.1038/nchem.1192
Yang, X., Zheng, Q., Gu, A., Lu, X.: Experimental studies of the performance of adsorbed natural gas storage system during discharge. Appl. Therm. Eng. 25(4), 591–601 (2004). https://doi.org/10.1016/j.applthermaleng.2004.07.002
Ybyraiymkul, D., Ng, K.C., Kaltayev, A.: Experimental and numerical study of effect of thermal management on storage capacity of the adsorbed natural gas vessel. Appl. Therm. Eng. 125, 523–531 (2017). https://doi.org/10.1016/j.applthermaleng.2017.06.147
Zhang, H., Deria, P., Farha, O.K., Hupp, J.T., Snurr, R.Q.: A thermodynamic tank model for studying the effect of higher hydrocarbons on natural gas storage in metal-organic frameworks. Energy Environ. Sci. 8, 1501–1510 (2015)
Acknowledgements
The work was supported by the Russian Ministry of Education and Science in the framework of the Federal Target Program “Research and development on priority directions of a scientific and technological complex of Russia for 2014–2020”. Agreement No. 14.607.21.0079, project identifier: RFMEFI60714X0079.
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Shkolin, A.V., Fomkin, A.A., Men’shchikov, I.E. et al. Monolithic microporous carbon adsorbent for low-temperature natural gas storage. Adsorption 25, 1559–1573 (2019). https://doi.org/10.1007/s10450-019-00135-0
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DOI: https://doi.org/10.1007/s10450-019-00135-0