Log in

A Theoretical and Experimental Study of Charge and Discharge Cycles in a Storage Vessel for Adsorbed Natural Gas

  • Published:
Adsorption Aims and scope Submit manuscript

Abstract

This study presents experimental data of storage and delivery tests of methane on activated carbon carried out in a prototype vessel at pressures up to 40 atm. Adsorption equilibrium data at high pressure were measured using a gravimetric apparatus. Experimental data obtained from the storage/delivery tests are compared to those obtained from process simulation using a dynamic model. The simulation model was run using the measured equilibrium data as input parameters. A good agreement was observed between experimental and simulated results. Histories of pressure and stored mass were satisfactorily well predicted. Despite heat effects, not precisely taken into account in the model, there was a reasonably good agreement between simulation and experiment for the average temperature inside the vessel.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Alcañiz-Monge, J., M.A. De la Casa-Lillo, D. Cazorla-Amorós, and A. Linares-Solano, “Methane Storage in Activated Carbon Fibres,” Carbon, 35(2), 291–297 (1997).

    Google Scholar 

  • Araújo, J.C.S., Estudo de Equilíbrio de Adsorção em Altas Pressões de Metano em Carvão Ativado, M.Sc. Thesis, Fortaleza: Universidade Federal do Ceará, (2004).

  • Biloé, S., V. Goetz, and A. Guillot, “Optimal Design of an Activated Carbon for an Adsorbed Natural Gas Storage System,” Carbon, 40(8), 1295–1308 (2002).

    Google Scholar 

  • Biloé, S., V. Goetz, and S. Mauran, “Dynamic Discharge and Performance of a New Adsorbent for Natural Gas Storage,” AIChE J., 47(12), 2819–2830 (2001).

    Google Scholar 

  • Cook, T.L., C. Komodromos, D.F. Quinn, and S. Ragan, In: T.D. Burchell, Editor, Carbon Materials for Advanced Technologies, Pergamon, New York, 269–302 (1999).

  • Cracknell, R.F., P. Gordon, and K.E. Gubbins, “Influence of Pore Geometry on the Design of Microporous Materials for Methane Storage,” J. Physical Chemistry, 97, 494–499 (1993).

    CAS  Google Scholar 

  • Chang, K.J. and O. Talu, “Behavior and Performance of Adsorptive Natural Gas Storage Cylinders During Discharge,” Applied Thermal Engineering, 16(5), 359–374 (1996).

    Article  CAS  ISI  Google Scholar 

  • Do, D.D. and H.D. Do, “Adsorption of Supercritical Fluids in Non-Porous and Porous Carbons: Analysis of Adsorbed Phase Volume and Density,” Carbon, 41,(9), 1777–1791 (2003).

    Article  CAS  ISI  Google Scholar 

  • Dreisbach, F., H.W. Lösch, and P. Harting, “Highest Pressure Adsorption Equilibria Data: Measurement with Magnetic Suspension Balance and Analysis with a New Adsorbent/Adsorbate-Volume,” Adsorption, 8(2), 95–109 (2002).

    Article  CAS  ISI  Google Scholar 

  • Lozano-Castelló, D., J. Alcaniz-Monge, M.A. de la Casa-Lillo, D. Cazorla-Amorós, and A. Linares-Solano, “Advances in the Study of Methane Storage in Porous Carbonaceous Materials,” Fuel, 81(14), 1777–1803 (2002).

    Google Scholar 

  • Menon, V.C. and S. Komarneni, “Porous Adsorbents for Vehicular Natural Gas Storage: A Review,” J. Porous Materials, 5, 43–58 (1998).

    CAS  Google Scholar 

  • Mota, J.P.B., “Impact of Gas Composition on Natural Gas Storage by Adsorption,” AIChE J., 45(5), 986–996 (1999).

    Article  CAS  Google Scholar 

  • Mota, J.P.B., A.E. Rodrigues, E. Saatdjian, and D. Tondeur, “Charge Dynamics of a Methane Adsorption Storage System: Intraparticle Diffusional Effects,” Adsorption, 3(2), 117–125 (1997a).

    CAS  ISI  Google Scholar 

  • Mota, J.P.B., A.E. Rodrigues, E. Saatdjian, and D. Tondeur, “Dynamics of Natural Gas Adsorption Storage Systems Employing Activated Carbon,” Carbon, 35(9), 1259–1270 (1997b).

    Article  CAS  ISI  Google Scholar 

  • Mota, J.P.B., E. Saatdjian, D. Tondeur, and A.E. Rodrigues, “A Simulation Model of a High-Capacity Methane Adsorptive Storage System,” Adsorption, 1(1), 17–27 (1995).

    CAS  ISI  Google Scholar 

  • Parkyns, N.D. and D.F. Quinn, in: J.W. Patrick, Editor, Porosity in Carbons, Edward Arnold, London, 293–325 (1995).

  • Process System Enterprise Ltd. gPROMS v1.7 User Guide., London, 1999.

  • Pupier, O., V. Goetz, and R. Fiscal, “Effect of Cycling Operations on an Adsorbed Natural Gas Storage,” Chemical Engineering and Processing, 44(1), 71–79 (2005).

    Article  CAS  ISI  Google Scholar 

  • Vasiliev, L.L., L.E. Kanonchik, D.A. Mishkinis, and M.I. Rabetsky, “Adsorbed Natural Gas Storage and Transportation Vessels,” Int. J. Thermal Sciences, 39(9–11), 1047–1055 (2000).

    CAS  Google Scholar 

  • Ustinov, E.A., D.D. Do, A. Herbst, R. Staudt, and P. Harting, “Modeling of Gas Adsorption Equilibrium over a Wide Range of Pressure: A Thermodynamic Approach Based on Equation of State,” J. Colloid and Interface Science, 250, 49–62 (2002).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Diana C. S. Azevedo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bastos-Neto, M., Torres, A.E.B., Azevedo, D.C.S. et al. A Theoretical and Experimental Study of Charge and Discharge Cycles in a Storage Vessel for Adsorbed Natural Gas. Adsorption 11, 147–157 (2005). https://doi.org/10.1007/s10450-005-4906-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10450-005-4906-y

Keywords

Navigation