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Palladium carboxylate π-complexes with unsaturated hydrocarbons and the reactions catalyzed by them
This review summarizes the studies on the palladium carboxylate π-complexes with unsaturated hydrocarbons (alkenes, alkynes, and arenes) as well as...
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Synthesis, Structural Elucidation and DNA-Binding Studies of Centrosymmetric Paddlewheel Copper Carboxylate Complexes
Synthesis, characterization and structural relevance of four new copper carboxylate complexes ( 1 – 4 ) has been presented here. The complexes have been...
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Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes
AbstractNew pentanuclear complexes [Cu 3 M 2 (CHF 2 COO) 12 (H 2 O) 8 ]·2H 2 O, where M = Er ( I ) and Nd ( II ), were synthesized by reacting individual copper...
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Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands
AbstractNew bimetallic pivalate Pd(II) complex [PdNi(OOC t Bu) 4 (HOOC t Bu)] ( I ) has been synthesized from [PdNi(OOCMe) 4 ] and used as a starting reagent...
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Intramolecular force field for carboxylate Pt(II)-complexes
Force-field parameters are required for classical molecular dynamics (MD) simulations. Generally, these force fields are well described for organic...
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Melt-quenched carboxylate metal–organic framework glasses
Although carboxylate-based frameworks are commonly used architectures in metal-organic frameworks (MOFs), liquid/glass MOFs have thus far mainly been...
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Synthesis, Structure, and Biological Activity of New Metal Carboxylate Complexes Containing a Glycoluril Fragment
AbstractCu(II), Ni(II), Zn(II), Co(II), Fe(II), Mn(II) carboxylates containing a pharmacophoric glycoluril fragment were obtained for the first time....
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Relationships between carboxylate-based nutrient-acquisition strategies, phosphorus-nutritional status and rare earth element accumulation in plants
Background and aimsWe explored how phosphorus (P) availability influences accumulation of rare earth elements (REE) in plant species with different...
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Melt-quenched glass formation of a family of metal-carboxylate frameworks
Metal-organic framework (MOF) glasses are an emerging class of glasses which complement traditional inorganic, organic and metallic counterparts due...
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The role of root carboxylate release on rare earth element (hyper)accumulation in plants – a biogeochemical perspective on rhizosphere chemistry
The paper of van der Ent et al. (Plant Soil 485:247–257,
2023 ), published in the previous issue, reports the hyperaccumulation of rare earth elements...
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Soil controls on carboxylate-driven processes and opportunities
Through their influence on microbial processes, carboxylates exuded by roots are key drivers of nutrient acquisition and organic carbon (C) storage...
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Synthesis, Structural, DFT, and Antimicrobial Studies of Some Cefprozil Complexes
AbstractCefprozil complexes with Co(II), Ni(II), Zn(II), Mn(II), Cr(III), Fe(III) and Cu(II) were synthesized. Structure of the synthesized complexes...
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Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes
AbstractThe effect of bulky tridentate ligands on the geometry of carboxylate complexes was studied in relation to...
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Mononuclear Metal Complexes of Moxifloxacin with Antacids: Synthesis, Spectroscopic Characterization, and Antimicrobial Activities
Mononuclear metal complexes of 1-cyclopropyl-7-[( S , S )-2,8-diazabicyclo[4.3.0]non-8-yl]-6-fluoro-8-methoxy-1,4-dihydro-4-oxo-3-quinoline carboxylic...
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Polyelectrolyte Complexes
This chapter presents selected ideas concerning complexes that are formed either by oppositely charged polyelectrolytes or by polyelectrolytes and...
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Self-assembled discrete and polymeric cobalt(II) complexes of a carboxylate appended tripodal tetradentate ligand: reactivity with aerial dioxygen or aqueous hydrogen peroxide
Three new cobalt(II) complexes [Co(µ 2 - L )] 3 (ClO 4 ) 3 . 2H 2 O, 1 , [Co( L )(NO 3 )], 2 and {[Co(µ 2 - L )(MeOH)](BPh 4 ) . (MeOH)} n , 3 are prepared where L stands for...
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Exploration of Optical and Radiative Properties of Fluorinated β-keto Carboxylate Tb3+ Complexes Emanating Cool Green Light
Tb 3+ complexes with β-ketocarboxylic acid as main ligand and heterocyclic systems as auxiliary ligand were synthesized and analyzed to assess their...
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Desolvation of metal complexes to construct metal–organic framework glasses
Structural design is an important challenge in glassy materials, including metal–organic framework (MOF) glasses. The current approaches of thermal...
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Prolonged corrosion protection via application of 4-ferrocenylbutyl saturated carboxylate ester derivatives with superior inhibition performance for mild steel
A series of 4-ferrcenylbutyl carboxylate esters with different alkyl chain length (C 2 -C 4 ) of carboxylic acids were synthesized using Fe 3 O 4 @SiO 2 @(CH 2 ) 3 ...
