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Novel semi-aromatic polyamides containing ether bond and pendant methyl group: synthesis and properties
Through synthesizing novel difluoro-monomer (1,6-N,N’-bis(4-fuorobenzamide) trimethylhexane (BFBT)) and adjusting the structure of bisphenol monomer...
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Cage octasilsesquioxane-pendant polynorbornenes connected with short spacers exhibiting optical transparency
Heptaisobutyl-norbornenylethyl-substituted cage octasilsesquioxane (POSS) ( 1a ) and heptaphenyl-norbornenylethyl-substituted POSS ( 1b ) were subjected...
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Mechanochemical Synthesis of closo-Decaborate Anion Derivatives with Pendant Functional Groups
Astract―A new method for the preparation of derivatives of the closo -decaborate anion with pendant functional groups has been developed, which...
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The extremal irregularity of connected graphs with given number of pendant vertices
The irregularity of a graph G = ( V, E ) is defined as the sum of imbalances ∣ d u − d v ∣ over all edges uv ∈ E , where d u denotes the degree of the vertex u ...
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Thermo- and pH-sensitive Polymer with Pendant Spacer-linked Imidazole Cycles
By the reaction of poly(acryloyl chloride) with N -(3-aminopropyl)imidazole, poly( N -(3-(1 H -imidazol-1-yl)propyl)acrylamide) was synthesized. The new...
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Cellulose polymers with β-amino ester pendant group: design, synthesis, molecular docking and application in adsorption of toxic metals from wastewater
BackgroundCellulose polymers with multidentate chelating functionalities that have high efficiency for toxic metal ions present in water were...
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Development of Photocrosslinkable Polymers Containing Chalcone as Pendant Photosensitive Moieties
AbstractNew photocrosslinking polymers based on photoreactive methacrylate derivatives copolymerized with styrene and maleic anhydride were...
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Recent advances in visible light-induced C(sp3)–N bond formation
Synthetic chemists have long focused on selective C( sp 3 )–N bond-forming approaches in response to the high value of this motif in natural products,...
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Phosphorus-nitrogen compounds: Part 69—Unsymmetrical dispiro(N/N)cyclotriphosphazenes containing different pendant arms: syntheses, characterization, stereogenism, photophysical and bioactivity studies
In this research, the starting compounds tetrachloromonospirocyclotriphosphazenes, (BzSpiro-5)R 1 (N 3 P 3 )Cl 4 [Bz: Benzyl; R 1 : Me ( 1 ) and R 1 : Et ( 2 )],...
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A Study of Abraham’s Effective Hydrogen Bond Acidity and Polarity/Polarizability Parameters, A and S, Using Computationally Derived Molecular Properties
Abraham’s hydrogen bond donor and polarity/polarizability parameters, A and S , respectively, are correlated with molecular properties derived from...
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Development of a radical polymerization algorithm for molecular dynamics simulations of antifreezing hydrogels with double-network structures
The development and understanding of antifreezing hydrogels are crucial both in principle and practice for the design and delivery of new materials....
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Synthesis of degradable polymers via 1,5-shift radical isomerization polymerization of vinyl ether derivatives with a cleavable bond
We report a novel method for synthesizing degradable polymers based on 1,5-shift radical isomerization polymerizations of vinyl ethers with...
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On the Absence of Cyclic Structures in Branched Polystyrenes Synthesized by Living Three-Dimensional Radical Polymerization in the Medium of a Deteriorating Thermodynamic Quality Solvent
AbstractBranched polystyrenes are synthesized by the radical copolymerization of styrene and divinylbenzene with reversible inhibition (in the...
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Phosphorus–nitrogen compounds: part 53—synthesis, characterization, cytotoxic and antimicrobial activity, DNA interaction and molecular docking studies of new mono- and dispirocyclotriphosphazenes with pendant arm(s)
Mono-/dispirocyclotriphosphazenes with pendant arm(s) are robust, but they are less investigated inorganic ring systems. In this study, a series of...
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Design automation of microfluidic single and double emulsion droplets with machine learning
Droplet microfluidics enables kHz screening of picoliter samples at a fraction of the cost of other high-throughput approaches. However, generating...
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Stereospecific syn-dihalogenations and regiodivergent syn-interhalogenation of alkenes via vicinal double electrophilic activation strategy
Whereas the conventional anti -dihalogenation of alkenes is a valuable synthetic tool with highly predictable stereospecificity, the restricted...
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Properties evaluation of double silane system compound gel as a protective coating on concrete
Inhibiting moisture transfer at the surface of concrete plays a vital role on the durability of concrete, and permeable protective coating can...
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Hydrogen-bond-acceptor ligands enable distal C(sp3)–H arylation of free alcohols
The functionalization of C–H bonds in organic molecules is one of the most direct approaches for chemical synthesis. Recent advances in catalysis...
