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Photo-induced surface frustrated Lewis pairs for promoted photocatalytic decomposition of perfluorooctanoic acid
Heterogeneous photocatalysis has gained substantial research interest in treating per- and polyfluoroalkyl substances (PFAS)-contaminated water....
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B(C6F5)3-based Lewis pair-catalyzed acrylate polymerization: Lewis base effects on pairing interactions
Acrylate polymerizations catalyzed by Lewis pairs (LP) composed of B(C 6 F 5 ) 3 and various Lewis bases (phosphines, amines, and an N-heterocyclic...
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Comparative Selective Conversion of Biomass-Derived Mono- and Polysaccharides into Lactic Acid with Lanthanide Lewis Acid Catalysts
Lanthanides were tested (Ce 3+ , Er 3+ , and Yb 3+ ) as catalysts to produce lactic acid (LA) from the monosaccharides present in corn stover (glucose,...
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Lewis acid-mediated Suzuki–Miyaura cross-coupling reaction
The palladium-catalysed Suzuki–Miyaura cross-coupling reaction of organohalides and organoborons is a reliable method for carbon–carbon bond...
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Research progress in the living/controlled polymerization of (meth)acrylate monomers by Lewis pair
Lewis pair polymerization (LPP) has demonstrated its unique advantages, such as high activity, high stability, and adjustable variability, towards...
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Balanced acidity by microwave-assisted ion-exchange of ZSM-5 zeolite as a catalyst for transformation of glucose to levulinic acid
Levulinic acid (LA) is a worthwhile biochemical usable as a building-block for the formation of wide variety of chemicals and fuels. In the present...
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Multilayer Nb2CTx (MXene) Supports CoB for the Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol: Effect of the Electron-Modified CoB Site and Lewis Acid Site
A heterogeneous CoB/Nb 2 CT x catalyst was successfully prepared by in situ wet reduction of Co metal ions electrostatically adsorbed on the surface of...
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Frustrated Lewis pair catalyst realizes efficient green diesel production
Hydrotreating renewable oils over sulfided metal catalysts is commercially applied to produce green diesel, but it requires a continuous sulfur...
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High-density frustrated Lewis pairs based on Lamellar Nb2O5 for photocatalytic non-oxidative methane coupling
Photocatalytic methane conversion requires a strong polarization environment composed of abundant activation sites with the robust stretching ability...
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The Influence of the Local Environment on the Electron Accepting Ability of the Cation: Induced Lewis Acidity
AbstractThe effect of adsorption of acid gases CO 2 , SO 2 , and SO 3 on the electron accepting ability of cations on the surface of calcium oxide was...
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Dolomitisation favoured by Lewis acidic background compounds in saline fluids
Predicting the type and rate of reactions between minerals and fluids is of utmost importance in many applications. Due to the presence of background...
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Lewis acid-catalyzed Diels–Alder cycloaddition of 2,5-dimethylfuran and ethylene: a density functional theory investigation
Density functional theory calculations with the M06-2X exchange–correlation functional have been performed to explore the Diels–Alder reaction...
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Asymmetric synthesis of N-bridged [3.3.1] ring systems by phosphonium salt/Lewis acid relay catalysis
Optically pure pseudo-natural products (PNPs), particularly exemplified by azabicyclo[3.3.1]nonane molecules and their analogs provide an attractive...
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Enantioconvergent construction of stereogenic silicon via Lewis base-catalyzed dynamic kinetic silyletherification of racemic chlorosilanes
Organosilanes possessing an enantioenriched stereogenic silicon center are important in many branches of chemistry, yet they remain challenging to...
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Collective synthesis of acetylenic pharmaceuticals via enantioselective Nickel/Lewis acid-catalyzed propargylic alkylation
Chiral acetylenic derivatives are found in many bioactive compounds and are versatile functional groups in organic chemistry. Here, we describe an...
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Shedding Light on the Lewis Acid Catalysis in Organic Transformations Using a Zn-MOF Microflower and Its ZnO Nanorod
The Lewis acidic nature of both {[Zn 4 (µ 3 -OH) 2 ( d -2,4-cbs) 2 (H 2 O) 4 ] . 5H 2 O} n (Zn-CBS ) and its ZnO nanostructures ( ZnO_1 , 3D microflower; ZnO_2 , 3D...
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Hints for a formal language inspired by Lewis structures
In this work we elaborate on the idea of a formal theory for a limited but important part of structural chemistry, that described by Lewis’ methods...
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Micro–mesoporous kaolin-based zeolites as catalysts for glucose transformation into 5-hydroxymethylfurfural
A number of biporous granulated acid faujasite-type zeolite-containing catalysts based on Ukrainian kaolin were in situ synthesized. The samples were...
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Glycerol Transformation over Zeolite-Based Catalysts into Diverse Valuable Chemicals: A review
The utilization of fossil fuels has been the leading choice in the industrial revolution despite its negative environmental impact. Biodiesel is a...
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Unveiling novel reactivity of P/Al frustrated Lewis pair: ring size-dependent activation of cyclic ethers/thioethers and CO2 insertion therein
Rational design strategies for the Lewis acid and Lewis base functionalities have been probed using a series of “frustrated Lewis pairs” (FLPs)...
