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Hydrophobic Sn–Ti submicrospheres for cyclohexanone Baeyer–Villiger efficient oxidation
In this paper, hydrophobic treatment by hexadecetyltrimethoxysilane (HDTMS) on the surface of Sn–Ti submicrospheres with regular morphology and...
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Lipase-mediated Baeyer–Villiger oxidation of benzylcyclopentanones in ester solvents and deep eutectic solvents
This work presents the chemo-enzymatic Baeyer–Villiger oxidation of α-benzylcyclopentanones in ester solvents as well as deep eutectic solvents...
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Al-containing Ge-rich IWV: rapid synthesis via interzeolite transformation and application in Baeyer-Villiger oxidation
Ge-containing Lewis acidic zeolites are typically synthesized using a conventional hydrothermal strategy from amorphous silica sources, through a...
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Baeyer–Villiger oxidation of cyclic ketones with H2O2 over mesoporous Sn- and Zr-BEA zeolites
A set of Sn- and Zr-BEA zeolites was obtained using Gemini-type surfactants as SDA and hierarchical BEA nanosheets as seeds. The prepared catalysts...
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Features of the Baeyer—Villiger reaction in the case of a complex variously functionalized substrate
The reactions of (3 S ,4 RS )-1,3-dideoxy-3-[(2 Z )-4-methoxy-3-methyl-4-oxobut-2-en1-yl]-4- C -methyl-4,5- O -(1-methylethylidene)pent-2-ulose with MCPBA and...
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Mechanism and dynamics of Baeyer–Villiger oxidation of furfural to maleic anhydride in presence of H2O2 and Au clusters
ContextThe increasing demand for fuels and chemicals in the world has prompted the exploration of various forms of renewable energy resources. Using...
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Rhenium-containing compound(PyHReO4): synthesis, characterization and catalytic application in olefin epoxidation and baeyer-villiger oxidation
A novel compound based on catalytic functional metal rhenium, pyridinium perrhenate(PyHReO 4 ) was synthesized and characterized. The pyridinium...
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Immobilization of Baeyer–Villiger monooxygenase from acetone grown Fusarium sp.
ObjectiveA novel biocatalyst for Baeyer–Villiger oxidations is necessary for pharmaceutical and chemical industries, so this study aims to find a...
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Baeyer–Villiger Oxidation
General scheme: -
Oxidation of Cage Derivatives of Quinopimaric Acid
AbstractThe oxidation of cage compounds derived from quinopimaric acid, namely γ-diketone, oxa-“bird cage,” 18-chloro-15-oxa-“bird cage,” and...
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Ni-Zn supported defective carbon with multi-functional catalytic sites for Baeyer–Villiger reaction using air as oxidant
AbstractThe development of economic catalysts for aerobic oxidation procedure has attracted extensive attention. In this work, a novel Ni/Zn...
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Post-functionalization of dibenzothiophene to functionalized biphenyls via a photoinduced thia-Baeyer-Villiger oxidation
The Baeyer-Villiger reaction is used extensively in organic chemistry. Sila- and bora-variants have also been documented widely, with these processes...
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Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters
AbstractPathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling...
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A Baeyer-Villiger monooxygenase from Cupriavidus basilensis catalyzes asymmetric synthesis of (R)-lansoprazole and other pharmaco-sulfoxides
AbstractBiocatalytic synthesis of pharmaco-chiral sulfoxides has gained interest in recent years for its environmental friendliness. However, only a...
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Dakin Oxidation
Oxidation of aryl aldehydes or aryl ketones to phenols using basic hydrogen peroxide conditions. Cf. A variant of the Baeyer–Villiger oxidation. -
Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Acid Ionic Liquids
A series of amino-acid-based ionic liquids was synthesized via one-step protonation of the corresponding L -amino acid by utilizing an array of proton...
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Chemoenzymatic total synthesis of alchivemycin A
Alchivemycin A belongs to a unique class of polyketide natural products isolated from plant-derived actinomycete Streptomyces . It shows potent...
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Baeyer–Villiger Oxidation of Diastereomeric Michael Adducts of Levoglucosenone into Dilactones
AbstractThe oxidation of diastereomeric Michael adducts of levoglucosenone and cyclohexanone with 5 equiv of H 2 O 2 in isopropanol at 60°C results in...
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Biochemical and structural insights of multifunctional flavin-dependent monooxygenase FlsO1-catalyzed unexpected xanthone formation
Xanthone-containing natural products display diverse pharmacological properties. The biosynthetic mechanisms of the xanthone formation have not been...
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Oxidation und Reduktion
Oxidationen und Reduktionen befassen sich hauptsächlich mit der Transformation von C-O-Bindungen, also der Bildung und Umsetzung von Alkoholen und...