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Arylation Reactions via C-H Bond Cleavage
Various carbon nucleophiles having acidic C–H bonds, including active methylene compounds, ketones, aldehydes, esters, and so on, are arylated with...
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Palladium-Catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds
For many years, unactivated alkyl electrophiles that contain β hydrogens were generally regarded as unsuitable partners for palladium-catalyzed...
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Macrocycle Synthesis Through Templation
This review highlights the major advances over the last 5 years in the templated synthesis of carbon-based macrocycles. With selected examples, it...
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Recent Advances in the Chemistry of Difunctionalized Organo-Phosphorus and -Sulfur Compounds
Recent results related to the synthesis and reactivity of organocompounds substituted by both phosphorus and sulfur functional groups are reviewed....
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Liquid Sulfur
The molecular composition as well as the physical properties (including spectra) of liquid sulfur Liquid Sulfur...
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Speciation and Thermodynamics of Sulfur Vapor
Sulfur vapor Sulfur vapor at temperatures of between 200 and 1000 °C consists of all molecules with 2–10 atoms, some...
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Spin Crossover in Iron(II) Tris(diimine) and Bis(terimine) Systems
Tris(diimine) and bis(terimine) iron(II) complex salts constitute one of the major classes of spin crossover systems. Both electronic and structural...
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Spin Crossover in Pyrazolylborate and Pyrazolylmethane Complexes
The electronic spin-state crossover observed upon cooling and at high-pressure in the iron(II) and cobalt(II) complexes formed with the HB(pz)3...
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Angular momentum and spectral decomposition of ring currents: aromaticity and the annulene model
By a widely accepted criterion, an aromatic (anti-aromatic) π-conjugated system is one that sustains a global diatropic (paratropic) ring current...
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Use of N,N-Coordinating Ligands in Catalytic Asymmetric C--C Bond Formations: Example of Cyclopropanation, Diels--Alder Reaction, Nucleophilic Allylic Substitution
Chiral N,N-coordinating ligands have been particularly synthesized for their use as metal chelates catalyzing asymmetric C-C bond formations....
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Materials Chemistry of Group 13 Nitrides
The OMVPE process has been used to grow thin films of group 13 nitrides, namely GaN, InN, and AlN. In recent years there has been a great deal of...
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Scanning Probe Microscopy Studies of Surface-Immobilised DNA/Oligonucleotide Molecules
Although most in vivo biomolecular recognition occurs in solution, in many practical situations (e.g., diagnostics, drug discovery and biosensing)...
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New Phosphorylated Hosts for the Design of New Supramolecular Assemblies
Development of chemistry around new phosphorylated hosts provides an interesting new area of investigations in the design of host-guest systems....
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Complexes with a Metal-Phosphorus Triple Bond
A survey of the existing complexes containing a transition metal-phosphorus triple bond is presented. Based on the different types of these...
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Prediction of Crystal Structures Using Evolutionary Algorithms and Related Techniques
Methods, evolutionary and systematic search approaches, and applications of crystal structure prediction of closest-packed and framework materials...
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Molecular Containers: Design Approaches and Applications
The design and synthesis of molecular containers is playing an increasing role in the selective removal and detection of species within solution. The...
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Structural and Electronic Properties of Selected Fulleride Salts
The study of strongly correlated electron systems is at the forefront of contemporary condensed matter research because such materials, which include...
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Thermal Spin Crossover in Mn(II), Mn(III), Cr(II) and Co(III) Coordination Compounds
This chapter considers thermal spin crossover occurring in transition metal compounds other than those of Fe(II), Fe(III) and Co(II). Unusual...
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Isokinetic and Isoequilibrium Relationships in Spin Crossover Systems
A thorough statistical mechanical analysis of sources of variations and correlations in ΔE 0 and ΔS 0 of spin crossover...