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Electrochemical fluorosulfation of perfluoroalkyl vinyl ethers
The reaction of perfluoroalkyl vinyl ethers with electrochemically generated peroxydisulfuryl difluoride produces a mixture of...
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Synthesis and studies of nucleophilic reactions of vicinal bis (fluorosulfonyloxy)perfluoroisononanes
The addition of peroxydisulfuryl difluoride (FSO 3 ) 2 to isomeric perfluoroisononenes (perfluoropropylene trimers) was studied. Isomers containing the...
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Reactions of electrophiles with polyfluorinated olefins
This chapter seeks to cover recent developments in the area of electrophilic reactions of polyfluorinated olefins. It contains sections on methods of...
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Synthesis of the perfluoroacetyldiisopropylmethyl radical
A stable trifluoroacetylperfluorodiisopropylmethyl radical has been prepared by interaction of the...
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The influence of the mercury and thallium atoms in organomercury and organothallium nitroxyl radicals on their reactivity
An increase is found in the reactivity of organomercury and organothallium nitroxyl mono- and biradicals of the imidazoline type in comparison with...
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Fluorosulfation of fluoroalkyl halides
The basic characteristics of fluorosulfation of fluoroalkylhalides (effect of the structure of the polyfluoroalkyl, nature of the halogen, acid...
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Fluoroaliphatic esters of fluorosulfonic acid. 5. Conjugate radical fluorosulfatohalogenation of higher fluoroolefins
A study has been made of the electrochemical fluorosulfation of perfluoro-2-alkenes in the presence of halogens, leading to the formation of...
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Fluoroaliphatic esters of fluorosulfonic acid. 1. Reactions of higher fluoroolefins with electrochemically generated peroxydisulfuryl difluoride
The electrolysis of fluorosulfonic acid in the presence of perfluoro-2-alkenes in an electrolyzer without a diaphragm results in the formation of a...
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Reaction of peroxydisulfuryl difluoride with fluoroalkyl halides
The replacement of bromine in perfluoroalkyl bromides by an FSO 2 O group by the action of (FSO 2 O) 2 occurs upon catalysis by Br 2 or HSO 3 F, while the...
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Relationship between reactivity and oxidizing power of halogen fluorosulfates and peroxidisulfuryl difluoride
1. Measurements of stationary potentials of platinum were used to quantitatively evaluate the oxidizing power of halogen fluorosulfates and...
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Synthesis and properties of 2-nitrosopolyfluoroalkyl fluorosulfates
1. Addition of nitrosyl fluorosulfate to the multiple bond of fluoroolefins was accomplished, and the previously unknown 2-nitrosopolyfluoroalkyl...
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Reactions of chlorine and bromine fluorosulfates with perfluoroalkyl halides in a strongly acidic medium
1. Chlorine fluorosulfate is more active than bromine fluorosulfate in the substitution reaction of halogen atom in alkyl halides by the fluorosulfate...
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Reaction of chlorine fluorosulfate with 1-trifluoromethoxy-1,2-dichlorotrifluoroethane and 1,2-dichlorohexafluoropropane
The reactivity of chlorine fluorosulfate increases with increasing acidity of the medium. In HSO 3 F/SbF 5 , chlorine fluorosulfate under mild conditions...
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Perfluoroazomethines with fluorosulfate groups
The pyrolysis of adducts of 2-nitrosopolyfluoroalkyl fluorosulfates with fluoroolefins gives previously unreported fluorosulfonyloxyfluoroazomethines.
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Reactivity of bromine tris(fluorosulfate)
1. In reactions of bromine tris (fluorosulfate) with fluoroolefins the corresponding 2-bromofluoroalkyl fluorosulfates and vicinal bis...
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Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins
Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β -chloroalkyl fluorosulfates together with 1,2-dichlorides....
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Reaction of chlorine fluorosulfate and peroxydisulfuryl difluoride with perfluoronitrosoalkanes
The replacement of the nitroso group in perfluoronitrosoalkanes in the presence of chlorine fluorosulfate and peroxydisulfuryl difluoride was...