Abstract
A stable trifluoroacetylperfluorodiisopropylmethyl radical has been prepared by interaction of the (α-fluorosulfonyloxytetrafluoroethyl)perfluorodiisopropylmethyl radical with anhydrous CsF. This reaction is the first example of a chemical transformation of a C-centered radical which is not resonance-stabilized with retention of the radical center.
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References
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Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 226–227, January, 1993.
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Avetisyan, E.A., Tumanskii, B.L., Cherstkov, V.F. et al. Synthesis of the perfluoroacetyldiisopropylmethyl radical. Russ Chem Bull 42, 207–208 (1993). https://doi.org/10.1007/BF00700014
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DOI: https://doi.org/10.1007/BF00700014