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Novel semi-aromatic polyamides containing ether bond and pendant methyl group: synthesis and properties
Through synthesizing novel difluoro-monomer (1,6-N,N’-bis(4-fuorobenzamide) trimethylhexane (BFBT)) and adjusting the structure of bisphenol monomer...
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Cage octasilsesquioxane-pendant polynorbornenes connected with short spacers exhibiting optical transparency
Heptaisobutyl-norbornenylethyl-substituted cage octasilsesquioxane (POSS) ( 1a ) and heptaphenyl-norbornenylethyl-substituted POSS ( 1b ) were subjected...
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Mechanochemical Synthesis of closo-Decaborate Anion Derivatives with Pendant Functional Groups
Astract―A new method for the preparation of derivatives of the closo -decaborate anion with pendant functional groups has been developed, which...
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Thermo- and pH-sensitive Polymer with Pendant Spacer-linked Imidazole Cycles
By the reaction of poly(acryloyl chloride) with N -(3-aminopropyl)imidazole, poly( N -(3-(1 H -imidazol-1-yl)propyl)acrylamide) was synthesized. The new...
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Cellulose polymers with β-amino ester pendant group: design, synthesis, molecular docking and application in adsorption of toxic metals from wastewater
BackgroundCellulose polymers with multidentate chelating functionalities that have high efficiency for toxic metal ions present in water were...
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Development of Photocrosslinkable Polymers Containing Chalcone as Pendant Photosensitive Moieties
AbstractNew photocrosslinking polymers based on photoreactive methacrylate derivatives copolymerized with styrene and maleic anhydride were...
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Recent advances in visible light-induced C(sp3)–N bond formation
Synthetic chemists have long focused on selective C( sp 3 )–N bond-forming approaches in response to the high value of this motif in natural products,...
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A Study of Abraham’s Effective Hydrogen Bond Acidity and Polarity/Polarizability Parameters, A and S, Using Computationally Derived Molecular Properties
Abraham’s hydrogen bond donor and polarity/polarizability parameters, A and S , respectively, are correlated with molecular properties derived from...
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Phosphorus-nitrogen compounds: Part 69—Unsymmetrical dispiro(N/N)cyclotriphosphazenes containing different pendant arms: syntheses, characterization, stereogenism, photophysical and bioactivity studies
In this research, the starting compounds tetrachloromonospirocyclotriphosphazenes, (BzSpiro-5)R 1 (N 3 P 3 )Cl 4 [Bz: Benzyl; R 1 : Me ( 1 ) and R 1 : Et ( 2 )],...
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Synthesis of degradable polymers via 1,5-shift radical isomerization polymerization of vinyl ether derivatives with a cleavable bond
We report a novel method for synthesizing degradable polymers based on 1,5-shift radical isomerization polymerizations of vinyl ethers with...
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On the Absence of Cyclic Structures in Branched Polystyrenes Synthesized by Living Three-Dimensional Radical Polymerization in the Medium of a Deteriorating Thermodynamic Quality Solvent
AbstractBranched polystyrenes are synthesized by the radical copolymerization of styrene and divinylbenzene with reversible inhibition (in the...
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Electrochemical, structural and thermal studies of poly (ethyl methacrylate) (PEMA)-based ion conductor for electrochemical double-layer capacitor application
Solid polymer electrolyte based on poly (ethyl methacrylate) (PEMA) and lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) was prepared for...
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Synthesis of sandwiched chitosan-g-PMMA nanocomposite by layered double hydroxides for packaging applications
Silver nanoparticles (AgNPs) incorporated layered double hydroxides (LDH) reinforced chitosan grafted polymethyl methacrylate nanocomposites...
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Catalytic isomerization of glucose to fructose over organic ligands: a DFT study
ContextIsomerization processes between glucose and fructose catalyzed by four different organic ligands are investigated with quantum chemistry...
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Synthesis of Functionized Polymethylhydrosiloxane via Pt-Catalyzed Hydrosilylation and the Effect of Substituents at the Olefin on the Reaction
The hydrosilylation of polymethyl-hydrosiloxane (PMHS) with alkenes comprising alkyl, epoxy alkyl, and other functional groups under the action of...
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A catenane that is topologically achiral despite being composed of oriented rings
Catenanes—molecules comprising two interlocking rings held together like links in a chain—are topologically non-trivial: a catenane is a topological...
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Synthesis and characterization of new methacrylate copolymers having pendant chloroacetophenon; monomer reactivity ratio, thermal degradation kinetics and biological activity
In this work, 2-(4-acetyl-2,6-dichloroanilino)-2-oxoethyl-2-methylprop-2-enoate (CFAOMA) monomer was synthesized and characterized. Then, copolymers...
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Self-Assembly of Gel-Like Particles and Vesicles in Solutions of Polymers with Amphiphilic Repeat Unit
AbstractThe features of self-assembly of amphiphilic homopolymers with solvophobic backbone and solvophilic pendant groups in dilute solutions have...
