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Dioxidomolybdenum(VI) Complex Supported on Chloromethylated Polymer and Its Catalytic Role in Peroxidase Mimicking Activity Towards Oxidation of Dopamine
Dioxidomolybdenum(VI) complex, [Mo VI O 2 (HL) 2 ] ( 1 ) using ligand H 2 L ( I ) (synthesised from o -phenylenediamine and salicylaldehyde) and it’s...
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Synthesis, Characterization and Biomimetic Activity of Heterogenized Dioxidomolybdenum(VI) Complex and Its Homogeneous Analogue
Cis -[Mo VI O 2 (CH 3 -hptb)(MeOH)] ( 1 ) has been synthesized by the reaction of [Mo VI O 2 (acac) 2 ] and deferasirox [ICL670:...
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A DFT study of the molecular and electronic structures of cis-dioxidomolybdenum (VI) complex of 8-hydroxyquinoline and 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one with water
Density functional theory approaches are employed to elucidate the structural features and electronic properties of cis -dioxidomolybdenum(VI)...
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Synthesis, structural insights and catalytic activity of a dioxidomolybdenum(VI) complex chelated with N4-(3-methoxyphenyl) thiosemicarbazone
A cis -dioxidomolybdenum(VI) complex of a thiosemicarbazone of the type [MoO 2 L(DMSO)], where H 2 L = 3-ethoxysalicylaldehyde-N 4 -(3-methoxyphenyl)...
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Synthesis, Characterization and Crystal Structures of Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes Derived from 2-bromo-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide with Catalytic Property
AbstractA hydrazone compound 2-bromo- N '-(2-hydroxy-3-methoxybenzylidene)benzohydrazide (H 2 L) was prepared and characterized by IR, UV-Vis and NMR...
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Synthesis, Spectral Characterization and Crystal Structures of Dioxidomolybdenum(VI) Complexes Derived from Nicotinoylhydrazones
AbstractCis -dioxidomolybdenum(VI) complexes [MoO 2 L 1 (DMSO)] ( 1 ), [MoO 2 L 2 (H 2 O)]·DMF ( 2 ) and [MoO 2 L 3 (DMF)] ( 3 ) were synthesized by solution based...
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Spectral studies and crystal structures of molybdenum(VI) complexes containing pyridine or picoline as auxiliary ligands: interaction energy calculations and free radical scavenging studies
Three cis- MoO 2 complexes [MoO 2 (CAB)(py)] ( 1 ), [MoO 2 (CAB)(3-pic)] ( 2 ) and [MoO 2 (CAB)(4-pic)] ( 3 ) which vary in the nature of the heterocyclic bases in...
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Sonochemical and solvothermal synthesis of methanol {2-[(2-hydroxy-1,1-dimethyl-ethylimino)-methyl]phenolato}-dioxidomolybdenum(VI) complex and its decomposition to MoO3 nanoparticles
As a new precursor to prepare nano molybdenum trioxide, methanol {2-[(2-hydroxy-1,1-dimethylethylimino)-methyl]phenolato}dioxidomolybdenum(VI)...
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Metal-Catalyzed Oxidation of C–H Compounds with Peroxides in Unconventional Solvents
This chapter describes some examples of oxidation of C‒H compounds (saturated and aromatic hydrocarbons and alcohols) with peroxides catalyzed by...