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Palladium-Catalyzed Mechanochemical Cross-Coupling Reactions
In this thesis, the author developed cross-coupling reactions that proceed in the solid state without using organic solvents, utilizing a...
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Palladium-Catalyzed Cross-Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds
For many years, unactivated alkyl electrophiles that contain β hydrogens were generally regarded as unsuitable partners for palladium-catalyzed...
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Evidence of Fast Activation of Unreactive Aryl Chlorides in Cross-Coupling Reactions
AbstractIt has been demonstrated that aryl chlorides traditionally showing low reactivity in cross-coupling reactions are able to compete...
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Palladium-Catalyzed Cross-Coupling Reactions in the Synthesis of Pharmaceuticals
The use of Pd-catalyzed cross-coupling methods for the construction of C-C, C-N, and C-O bonds have increased exponentially over the years. The...
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Solid-State Cross-Coupling Reactions of Insoluble Aryl Halides Under Polymer-Assisted Grinding Conditions
In this study, polymer-assisted grinding (POLAG), a ball milling technique based on the use of polymer additives, was applied to mechanochemical...
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Map** the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0)
The complexes of first-row transition metals can undergo elementary reactions by multiple pathways due to their propensity to undergo both one- and...
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Solid-State Suzuki–Miyaura Cross-Coupling Reaction Using Mechanochemistry
The Suzuki–Miyaura cross-coupling reaction is one of the most reliable methods for the construction of carbon–carbon bonds in solution. However,...
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Olefin-Accelerated Solid-State C–N Cross-Coupling Using Mechanochemistry
Palladium-catalyzed cross-coupling reactions are one of the most powerful and versatile methods to synthesize a wide range of complex functionalized...
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Pd-Complexes with Azanediylbis(1,2-azolyl)- and Bis(1,2-azolyl)carboxamide Ligands for Catalysis of Cross-Coupling Reactions in Aqueous Media
Abstract5-Arylisoxazolyl- and 4,5-dichloroisothiazolyl-3-carboxamides were synthesized based on trichlorethylene and its dimer. The prepared...
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Synthesis of Au–Pd@CeO2 nanocomposite as a potential catalyst for the Buchwald–Hartwig cross-coupling and amination of benzyl alcohol reactions
Herein, we report the novel protocol for synthesizing bimetallic gold and palladium nanoparticles decorated on rigid and stable cerium oxide support...
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Cu/photoredox-catalyzed decarboxylative radical C(sp3)-C(sp3) cross-coupling reactions
A radical decarboxylative C(sp 3 )-C(sp 3 ) cross-coupling of NHPI esters and cyclopropanols was developed by combining photocatalysis and copper...
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Heterogeneous Copper-Free Sonogashira Cross-Coupling Reactions Catalyzed by a Recyclable Orthopalladated Azo-Complex
In this work, the preparation of titania-supported Pd catalyst deriving from pincer-type orthopalladated azo-complex is presented. The new highly...
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Biomacromolecule supported N-heterocyclic carbene-palladium(II) as a novel catalyst for Suzuki–Miyaura and Mizoroki–Heck cross-coupling reactions
The field of catalysis is ever flourishing to meet the challenges faced in our day-to-day needs kee** in mind the environmental concerns. In line...
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Radical C(sp3)–H functionalization and cross-coupling reactions
C–H functionalization reactions are playing an increasing role in the preparation and modification of complex organic molecules, including...
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Nickel nanoparticles adorned on magnetized cellulose nanofibers: ultrasound-facilitated cross coupling reactions
An eco-friendly approach is described for the generation of Ni nanoparticles on a magnetized cellulose biopolymer wherein the adorned biopolymer...
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Palladium catalyst immobilized on functionalized hyper–cross-linked polymers with 8-hydroxyquinoline as monomer for Suzuki–Miyaura coupling reactions
An efficient and stable palladium species catalyst immobilized on functionalized hyper–cross-linked polymers (HCPs-Pd) has been successfully...
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Accessing three-dimensional molecular diversity through benzylic C–H cross-coupling
Pharmaceutical discovery efforts rely on robust synthetic methods that rapidly access diverse molecules. Cross-coupling reactions are the most widely...
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Synthesis, characterization and catalytic evaluation of three new Pd-iminophosphine complexes on Suzuki cross-coupling reactions
Three new palladium(II)-iminophosphine complexes, [Pd(L1)(Cl) 2 ] C1 , [Pd(L2)(Cl) 2 ] C2 and [Pd(L3)(Cl) 2 ] C3 have been synthesized and successfully...
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Chemoselective chromium-catalysed cross-coupling enables three-component tertiary alkane synthesis
The development of multiple-component cross-coupling reactions is a challenge due to issues of selectivity and efficiency. In the present study, we...
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Enantioselective C–C cross-coupling of unactivated alkenes
Metal-catalysed cross-coupling has played a central role in modern chemical synthesis for decades. Unactivated alkenes, including light olefins, are...
