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Electrochemical properties of (Co,Fe)CN, cobaltous Prussian blue analogue
A Prussian blue analogue (Co,Fe)CN with Fe and Co ions linked by CN – ions was synthesized; the synthesis was aimed at obtaining cobalt...
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Efficient Synthesis of Dimethyl Carbonate via Transesterification of Ethylene Carbonate Catalyzed by CN-SiAlO Composites
The transesterification reaction between ethylene carbonate (EC) and methanol is a sustainable method to produce dimethyl carbonate (DMC). As typical...
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Two-Temperature Analysis of Intensity Distribution in the Rovibronic Spectra of the CN Radical
AbstractThe effect of violation of the local thermodynamic equilibrium (LTE) on both the absolute values of intensities and intensity distribution in...
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Co(CN)3 catalysts with well-defined coordination structure for the oxygen reduction reaction
Metal-nitrogen-doped carbon (M-N-C) catalysts are promising platinum group metals alternatives for fuel cell cathodes; however, their randomly...
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Synthesis and Structure of Gold Complexes [Ph3PR][Au(CN)2Cl2] (R = CH2CH=CHCH3, CH2CN) and Ph3PC(H)(CN)Au(CN)2Cl
AbstractThe ionic complexes [Ph 3 PR][Au(CN) 2 Cl 2 ] (R = CH 2 CH=CHCH 3 ( I ), CH 2 CN ( II )) were prepared by the reactions of organyltriphenylphosphonium...
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A Kinetic Investigation of Hg(II) Catalyzed Cyanide Substitution from [Ru(CN)6]4– by Isoniazid
AbstractThe kinetics of Hg(II) accelerated substitution of cyanide with isoniazid (INH) from [Ru(CN) 6 ] 4– was investigated via measurement of the...
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Electrochemical determination of vanillin using 2D/2D heterostructure based on ZnCr-layered double hydroxide and g-CN
A ZnCr-LDH@g-CN composite was synthesized through a one-pot hydrothermal method to fabricate an effective sensor for detecting vanillin. The...
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Skeletal editing of pyridines through atom-pair swap from CN to CC
Skeletal editing is a straightforward synthetic strategy for precise substitution or rearrangement of atoms in core ring structures of complex...
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SPIN CROSSOVER IN IRON(II) COMPLEXES WITH TRIS(PYRAZOL-1-YL)METHANE AND [Ag(CN)2]– AND [Au(CN)2]– ANIONS
AbstractNew coordination compounds of iron(II) with tris(pyrazol-1-yl)methane (HC(pz) 3 ) containing dicyanoargentate and dicyanoaurate ions of the...
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Synthesis and Structure of the Ionic Complexes [Ph3PEt][Au(CN)2Cl2] and [Ph3PCH2CH2Br][Au(CN)2Br2]
AbstractThe reactions of potassium dichloro- and dibromodicyanoaurate with appropriate ethyl and (2‑bromoethyl)triphenylphosphonium halides in water...
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NIR-responsive CN-Pt-GEM hydrogel induces necroptosis and immunotherapeutic responses prevent postoperative recurrence and wound infection in lung carcinoma
BackgroundCancer recurrence following surgical resection is a major cause of treatment failure. Finding effective methods to prevent postoperative...
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Crystal Structure of the Cyano-Bridged Coordination Copper(I) Complex [Cu8(dpe)4(CN)8]·2dpe·H2O
AbstractCyano-bridged layered coordination polymer [Cu 8 (dpe) 4 (CN) 8 ]·2dpe·H 2 O ( 1 ) is prepared by the hydrothermal reaction of CuCN and dpe...
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Y4O2(CN2)3Cl2, Its Relation to the Metal-Rich Y2Cl3, and the Photoluminescence of Y4O2(CN2)3Cl2:Ce
Y 4 O 2 (CN 2 ) 3 Cl 2 and some isotypic rare earth ( RE ) carbodiimides RE 4 O 2 (CN 2 ) 3 Cl 2 ( RE = Sm, Gd, Tb) were prepared by solid-state metathesis reaction...
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Fabrication of 3d-4f Hetero-metallic Catalyst of Co/CN-CeO2 Incorporating Nitrogen-doped Carbon for High Performance Hydrogenation of Nitroarenes
Since catalytic hydrogenation of nitroarenes is of great significance in chemical industry, it is imperative to develop an inexpensive and efficient...
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Thermal Decomposition of [Ir(NH3)6][Fe(CN)6] in Various Atmospheres; Crystal Structures of [Ir(NH3)6][Fe(CN)6] and [Ir(NH3)6]
X 3 (X = Cl, Br)AbstractA new double complex salt [Ir(NH 3 ) 6 ][Fe(CN) 6 ] is synthesized and structurally characterized. The crystal structures of [Ir(NH 3 ) 6 ]Cl 3 and...
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Hollow CoZnSe@CN nanocage with enzymatic activity for determination of tetracycline using smartphone platforms and virtual reality revealing
Antibiotic residues in the environment pose a serious threat to ecosystems and human health. Therefore, it is important to develop sensitive and...
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CRYSTAL STRUCTURE OF (enH)(enH2)[{Cu2(μ-CN)}Re6S8(CN)6]
AbstractPorous framework coordination polymer (enH)(enH 2 )[{Cu 2 (μ-CN)}Re 6 S 8 (CN) 6 ] ( 1 ) is obtained by a reaction of Cs 2.67 K 1.33 [Re 6 S 8 (CN) 2 (OH) 4 ]·4H 2 O,...
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Synthesis and Structure of Gold Complexes [Ph3P(CH2)2CH2Br][Au(CN)2Br2], [Ph4Sb·(DMSO-O)][Au(CN)2Br2], and Ph3PC(H)(COOMe)Au(CN)2Cl
AbstractThe reactions of potassium dibromodicyanoaurate with (3-bromopropyl)triphenylphosphonium and tetraphenylstibonium bromides result in new...
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Schiff Base Derived CoPO–CN for Electrocatalytic Oxygen Evolution, Urea Oxidation and Ascorbic Acid Sensing
AbstractThe development of multifunctional electrocatalytic materials for energy storage, conversion and electrochemical sensing with the...
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Analysis of Local Perturbations on the “Red” and “Violet” Systems of the CN Radical
AbstractA nonadiabatic model is proposed that considers spin-orbit and electron-rotation coupling between three electronic states ( B 2 Σ + , А 2 Π, and Х 2 Σ
