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Crystal Structure of the Cyano-Bridged Coordination Copper(I) Complex [Cu8(dpe)4(CN)8]·2dpe·H2O

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Abstract

Cyano-bridged layered coordination polymer [Cu8(dpe)4(CN)8]·2dpe·H2O (1) is prepared by the hydrothermal reaction of CuCN and dpe (dpe = 1,2-di-4-pyridylethylene) in the presence of Cs3K[Re6S8(CN)6]·2H2O. The [Cu8(dpe)4(CN)8] complex is an isomer of the earlier described [Cu2(CN)2(dpe)] with a 3D framework structure. The structure of 1 is triclinic, \(P\bar{1}\) space group, a = 11.9229(8) Å, b = 11.9549(8) Å, c = 14.1984(10) Å, α = 102.019(2)°, β = 102.370(2)°, γ = 104.151(2)°, V = 1842.8(2) Å3, Z = 1, dcalc = 1.647 g/cm3. The Cu atoms in 1 have a triangular coordination environment formed by N atoms of the bridging dpe molecule and N and C atoms of the ambidentate bridging CN ligands.

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700321-3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, T. S. Sukhikh & Y. V. Mironov

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  1. A. V. Ermolaev
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  2. T. S. Sukhikh
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  3. Y. V. Mironov
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Correspondence to A. V. Ermolaev.

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 4, 125376.https://doi.org/10.26902/JSC_id125376

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Ermolaev, A.V., Sukhikh, T.S. & Mironov, Y.V. Crystal Structure of the Cyano-Bridged Coordination Copper(I) Complex [Cu8(dpe)4(CN)8]·2dpe·H2O. J Struct Chem 65, 771–775 (2024). https://doi.org/10.1134/S0022476624040127

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