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Heterometallic Coordination Assembly Catalysts RhIAgIL for Hydroformylation of Long-Chain Alkenes
An innovative bitopic phosphoramidite ligand L was proficiently synthesized and subsequently employed in coordination with two distinct metal species...
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Coordination Polymers of Cadmium with Di(pyrazol-1-yl)alkane-4,4'-dicarboxylic Acids: Synthesis, Crystal Structures, and Luminescence Properties
AbstractCoordination polymers of cadmium(II) with the di(pyrazol-1-yl)alkane derivatives, bis(3,5-dimethylpyrazol-1-yl)methane-4,4′-dicarboxylic acid...
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Studying the impact of NCS− anion and the steric hindrance of flexible N-donor ligands on the crystal engineering of the mercury(II) coordination polymer
Two novel coordination polymers, [Hg(bib Me )Cl 2 ] n (1), [Hg 3 (bib) 2 (NCS) 6 ] n (2), were prepared at room temperature by the reaction of appropriate salts...
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Porphyrin Supramolecules by Self-Complementary Coordination
The supramolecular organization of porphyrins using self-complementary coordination is reviewed. Complementarity affords large stability constants...
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Ni-Na Coordination Polymer Bridged by Dicyanamide: Synthesis, Structures, Spectra and Thermal Stability
One Ni(II)-Na(I) complex namely {[Ni II -L-Na I (dca)] 2 } n [H 2 L = 1,2-ethanediylbis(2-iminomethylene-6-methoxy-phenol)] was synthesized under mild...
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A NEW MELAMINE-BASED Cu(I) COORDINATION POLYMER WITH AN EXCELLENT PHOTOCATALYTIC ACTIVITY, THERAPEUTIC AND NURSING EFFECTS ON THE BLOOD GLUCOSE REGULATION
AbstractA novel Cu(I) coordination polymer [Cu 2 (MA) 2 Cl 2 ] n ( 1 , MA is melamine) is reported here. It is synthesized by hydrothermal reactions of CuCl...
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INVESTIGATION ON THE FLUORESCENT PROPERTY AND THE HIRSHFELD SURFACE ANALYSIS OF A NOVEL HETEROBIMETALLIC Cd(II)—Na(I) PYRIDINE-TERMINAL SALAMO-TYPE COORDINATION POLYMER
AbstractA novel heterometallic Cd(II)–Na(I) coordination polymer (Cd(II)–Na(I) CP), [{Cd(H 2 L)(OAc)(μ 2 -OAc)Na(OAc)(MeOH)(EtOH)} 2 ] n is self-assembled...
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Green synthesis of polyacrylamide/polyanionic cellulose hydrogels composited with Zr-based coordination polymer and their enhanced mechanical and adsorptive properties
As a class of typical supramolecular dynamic interactions, metal–ligand coordination has been widely used to fabricate high-performance hydrogels and...
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Polymers with [2,2′-Biquinoline]-diyldimethanamine Units in the Main Chain and Their Metal–Polymer Complexes with Copper(I)
AbstractNew monomers of the biquinoline series—diyldimethanamines—have been synthesized, and polymers having biquinoline units in the main chain and...
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A new Cu(II)-based coordination polymer: application values on liver cancer through down-regulating relative expression of miRNA9
In current research, a novel coordination polymer based on Cu(II) having a 1D spiro-like chain architecture has been created with the reaction...
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An electrochemical sensor based on carbon composites derived from bisbenzimidazole biphenyl coordination polymers for dihydroxybenzene isomers detection
Co-based coordination polymers (CoCP) based on 4,4′-bis(1H-benzo[d]imidazol-1-yl)-1,1′-biphenyl (BMB) ligand have been synthesized for the first...
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Dual-emission Tb-based coordination polymer as a ratiometric fluorescence probe for the detection of phosphate
A simple, sensitive dual-emission probe was developed for the detection of phosphate (Pi). The probe Tb-BTB/DPA was synthesized by mixing...
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Cu(I)-thioether coordination complexes based on a chiral cyclic β-amino acid ligand
Coordination complexes, particularly metalloproteins, highlight the significance of metal-sulfur bonds in biological processes. Their unique...
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Tuning the Dimensions of Coordination Polymers through Halogen Substituent Groups of Ligands
AbstractCoordination polymers were constructed using two ligands as a bi-linker to construct. The assistant ligand could tune the target...
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Anionic 3D Coordination Polymers of Zn(II) with 2,5-Diiodoterephthalate Bridging Ligands
Abstract3D coordination polymers of Zn(II) with 2,5-diiodoterephthalate linkers (DMA) 2 [Zn(2,5-I-bdc) 2 ]·1.5DMF ( 1 ) and K 2 [Zn(2,5-I-bdc) 2 ]·2DMF ( 2 )...
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3D Coordination Polymers with N-Heterocyclic Ga(I) Moieties
AbstractThe reactions of bimetallic acenaphthene-1,2-diimine complex [(Dpp-bian-GaCr(CO) 5 ] 2 -[Na(Thf) 2 ] 2 ( I ) (Dpp-bian =...
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Manganese(II)-based coordination polymer as a bi-responsive luminescent sensor for highly selective detection of picric acid and CrO42− ion
AbstractA novel luminescent coordination polymer (CP) {Mn(H 2 abtc)(DMF)(H 2 O) 2 ·2H 2 O} n (1), (H 4 abtc = 3,3′,5,5′-azobenzenete-tracarboxylic acid), has...
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Architectural View of Flexible Aliphatic –OH Group Coordinated Hemi-Directed Pb(II)-Salen Coordination Polymer: Synthesis, Crystal Structure, Spectroscopic Insights, Supramolecular Topographies, and DFT Perspective
AbstractWe serendipitously designed one novel 1D hetero-binuclear Zn(II)-Pb(II) coordination polymer, namely [(Zn)(Pb)(L)(η 1 –NCS)(η 1 –SCN)] n ( 1 ) from...
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The effect of ultrasonic irradiation power and initial concentration on the particle size of nano copper(II) coordination polymer: Precursors for preparation of CuO nanostructures
The general objective of this research was to study the effect of initial concentration of reactants and ultrasonic irradiation power impacts on the...
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A Three-Dimensional Cd(II)-Coordination Polymer: Crystal Structure, Electrochemiluminescent Property and Novel Topology
By employing 5-(pyridin-3-yl)-1 H -pyrazole-3-carboxylic acid ligand, a new coordination polymer [Cd(HPPC − ) 2 (H 2 O) 2 ] n ( 1 ) has been prepared via the...
