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Special Classes of Iron(II) Azole Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(II) spin crossover compounds of 1,2,4-triazole, isoxazole and tetrazole derivatives are... -
Electron Spin Resonance Spectroscopy
The theoretical principles of the ESR technique and its application in the field of molecular sieve science are reviewed. The first part of this... -
Determination of very broad particle size distributions via interference optics in the analytical ultracentrifuge
Dispersions play a big role in industry. Important characteristics such as viscosity and gloss depend on the particle size and the particle size... -
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DNA Electron Transfer Processes: Some Theoretical Notions
Charge motion within DNA stacks, probed by measurements of electric conductivity and by time-resolved and steady-state damage yield measurements, is... -
Valence Tautomeric Transition Metal Complexes
Valence d-orbital energies of the first row transition metals are close to the frontier π-orbital energies of o-benzoquinones. Complexes prepared... -
Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes
The interplay between the spin crossover and the structural properties of the complexes in the solid state is still under investigation. In... -
Intra-Solid and Inter-Solid Reactions of Molecular Crystals: a Green Route to Crystal Engineering
The thesis developed in this chapter is that reactions taking place between molecular solids or within molecular solids, or involving a molecular... -
Asymmetric Induction in Organic Photochemistry via the Solid-State Ionic Chiral Auxiliary Approach
After a brief introduction and summary of various methods of asymmetric induction in organic photochemistry, the main part of the review covers the... -
Monitoring Multidrug Resistance P-Glycoprotein Drug Transport Activity with Single-Photon Emission Computed Tomography and Positron Emission Tomography Radiopharmaceuticals
Multidrug resistance (MDR) mediated by overexpression of MDR1 P-glycoprotein (Pgp) is one of the best characterized transporter-mediated barriers to... -
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Spin Crossover in Iron(II) Tris(diimine) and Bis(terimine) Systems
Tris(diimine) and bis(terimine) iron(II) complex salts constitute one of the major classes of spin crossover systems. Both electronic and structural... -
Spin Crossover in Pyrazolylborate and Pyrazolylmethane Complexes
The electronic spin-state crossover observed upon cooling and at high-pressure in the iron(II) and cobalt(II) complexes formed with the HB(pz)3... -
Surface Modification of Polyethylene
Polyolefins such as polyethylene, polypropylene and their copolymers have excellent bulk physical/chemical properties, are... -
Angular momentum and spectral decomposition of ring currents: aromaticity and the annulene model
By a widely accepted criterion, an aromatic (anti-aromatic) π-conjugated system is one that sustains a global diatropic (paratropic) ring current... -
Materials Chemistry of Group 13 Nitrides
The OMVPE process has been used to grow thin films of group 13 nitrides, namely GaN, InN, and AlN. In recent years there has been a great deal of... -
Scanning Probe Microscopy Studies of Surface-Immobilised DNA/Oligonucleotide Molecules
Although most in vivo biomolecular recognition occurs in solution, in many practical situations (e.g., diagnostics, drug discovery and biosensing)... -
Molecular Containers: Design Approaches and Applications
The design and synthesis of molecular containers is playing an increasing role in the selective removal and detection of species within solution. The... -
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Effects of acetylation on thermodynamic properties of seaweed alginate in sodium chloride solutions
Alginates are polysaccharides consisting of mannuronate and guluronate units. While bacterial alginate is acetylated, seaweed alginate does not...