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  1. Article

    Open Access

    A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene

    Due to their intrinsic high reactivity, isolation of tin(0) complexes remains challenging. Herein, we report the synthesis of a silylene-stabilized ditin(0) complex (2) by reduction of a silylene-supported dibrom...

    Shaozhi Du, Fanshu Cao, ** Chen, Hua Rong, Haibin Song, Zhenbo Mo in Nature Communications (2023)

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  2. Article

    Open Access

    Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations

    Monovalent group 15 cations L2Pn + (L = σ-donor ligands, Pn = N, P, As, Sb, Bi) have attracted significant experimental and theoretical interest because of their unusual electronic structures and growing syntheti...

    Xuyang Wang, Binglin Lei, Zhaoyin Zhang, Ming Chen, Hua Rong… in Nature Communications (2023)

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