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  1. No Access

    Article

    A silylene-stabilized distannavinylidene with a highly labile substituent

    Vinylidene and its heavier analogues are fundamentally important in synthetic chemistry, but their stabilization and structural characterization remains extremely challenging. Herein we describe that the reduc...

    Zihao Qiao, Ming Chen, Zhenbo Mo in Science China Chemistry (2023)

  2. Article

    Open Access

    A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene

    Due to their intrinsic high reactivity, isolation of tin(0) complexes remains challenging. Herein, we report the synthesis of a silylene-stabilized ditin(0) complex (2) by reduction of a silylene-supported dibrom...

    Shaozhi Du, Fanshu Cao, ** Chen, Hua Rong, Haibin Song, Zhenbo Mo in Nature Communications (2023)

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  3. Article

    Open Access

    Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations

    Monovalent group 15 cations L2Pn + (L = σ-donor ligands, Pn = N, P, As, Sb, Bi) have attracted significant experimental and theoretical interest because of their unusual electronic structures and growing syntheti...

    Xuyang Wang, Binglin Lei, Zhaoyin Zhang, Ming Chen, Hua Rong… in Nature Communications (2023)

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