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Article
Open AccessGeneration and direct observation of a triplet arylnitrenium ion
Nitrenium ions are important reactive intermediates in both chemistry and biology. Although singlet nitrenium ions are well-characterized by direct methods, the triplet states of nitrenium ions have never been...
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Article
Isolation and reversible dimerization of a selenium–selenium three-electron σ-bond
Three-electron σ-bonding that was proposed by Linus Pauling in 1931 has been recognized as important in intermediates encountered in many areas. A number of three-electron bonding systems have been spectroscop...