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Article
Synthesis of new stereoregular 2,4,6,8-tetraphenylcyclotetrasiloxanes with mesogenic groups and the influence of spatial isomerism on the phase state of individual isomers and their mixtures
The hydrosilylation of four isomers of tetra(dimethylsiloxy)tetraphenylcyclotetrasiloxane with (4′-cyanobiphenyl-4-yl)undec-10-enoate in the presence of a platinum catalyst afforded four liquid-crystalline ste...
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Chapter
The Mesomorphic State of Flexible-Chain Polymers
Liquid-crystal polymers are frequently considered positionally disordered crystals or orientationally ordered liquids [1].
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Article
Effect of orientation stretch on structure of a composite fibre based on high-density polyethylene and polybutylene terephthalate
Due to the effect of the HDPE matrix in composite fibres based on HDPE-PBTP it is possible to draw the polybutylene terephthalate component to degrees of orientation which exceed the degree of orientation atta...
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Article
Rheological properties of a fibre-forming composition based on high-density polyethylene and polybutylene terephthalate
Composite fibres based on high-density polyethylene and polybutylene terephthalate have been prepared with different types of phase structure, depending on spinning conditions.
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Article
Formation of a phase structure of the “fibrils in matrix” type in a composite fibre based on high-density polyethylene and polyethylene terephthalate
Regions of component ratio and conditions for obtaining a composite fibre of the “fibrils in matrix” type have been determined for the HDPE-PET system.
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Article
Orientation stretching of a composite fibre based on high-density polyethylene and polyethylene terephthalate
An effect of the components on the possible stretch ratio of a composite fibre based on high-density polyethylene (HDPE) and polyethylene terephthalate (PET) has been detected, depending on the orientation str...
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Article
Thermodynamics of deformation of composites with polyvinyl chloride matrix
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Article
Energy investigation of the softening of siloxane rubbers during deformation
The softening of filled siloxane rubbers in tension is investigated from the energy standpoint. It is shown that during extension the starting structure of the rubber is converted into a new, energetically equ...
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Article
Investigation of the energy effects accompanying the elastic deformation of uniaxially oriented crystalline polymers
The energy (thermal and mechanical) effects accompanying the elastic deformation of uniaxially oriented crystalline polymers have been investigated; it has been established that, when these polymers are stretc...