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Article
Study on the impact resistance of prefabricated fractured red sandstone samples with different dip angles reinforced by bolt-grouting
With the development of underground engineering, dynamic disasters, such as rock bursts, are becoming increasingly serious. Bolt-grouting combined support is one of the common support methods, aiming at the pr...
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Article
Nonlinear Constitutive Model of Rock Joint in Geological Structure and Application of Implicit Return Map** Algorithm
As a common geological structure, rock joints have a great influence on the mechanical properties and stability of rock mass engineering. The shear constitutive model of the rock joint and its calculation meth...
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Article
Analysis of Shear Characteristics of Cohesive Soil and Rigid Base: A Case Study of Concrete Base
Taking the concrete as an example, this paper studies the shear characteristics of the cohesive soil and rigid base. A series of shear tests are conducted by the refitted DSJ-2 electric four-joint equal stress...
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Article
Study on Improved Nonlinear Viscoelastic-Plastic Creep Model Based on the Nishihara Model
The description of rock creep by existing rheological models mainly focuses on the first two stages of creep. However, the description of the accelerated creep stage is rare, which is contrary to the common st...
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Article
Correction to: Study on sandstone creep properties of Jushan Mine affected by degree of damage and confining pressure
The published version of this article unfortunately contained a mistake in Equation 8. Some of the symbols were not captured in the pdf version of the article. The correct Equation is presented below. The orig...
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Article
Study on sandstone creep properties of Jushan Mine affected by degree of damage and confining pressure
Creep characteristics of rock mass are related not only to the confining pressure but also to the degree of internal fracture damage. Revealing the creep characteristics of rock mass under different confining ...
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Article
Experiment and Study on Mechanical Property of Sandstone Post-peak Under the Cyclic Loading and Unloading
Engineering research has shown that the surrounding rock of deep roadways experienced many times of post-peak cyclic loading and unloading. So studying on rock mechanical characteristics of post-peak loading a...
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Article
Synaptic plasticity in the facial nucleus in rats following infraorbital nerve manipulation after facial nerve injury
The aim of this study is to investigate the effect of sensory input on the neural plasticity in the facial nucleus following facial nerve injury. Adult male Wistar rats were randomly assigned to four groups: (...
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Article
IRC analysis of methanol carbonylation reaction catalyzed by rhodium complex
In the reaction cycle for methanol carbonylation catalyzed by Rh complex, the structure geometries of the reactant, intermediates, transition states and product of each elemental reaction have been studied by ...
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Article
Implementation of a microcanonical variational transition state theory for direct dynamics calculations of rate constants
An implementation of the variational quantum RRKM program is presented to utilize the direct ab initio dynamics approach for calculating k(tE, J), k(E) and k(T) within the framework of the microcanonical transiti...
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Article
Ab initio study on the mechanism of reaction HNCO+NH2
Ab initio UMP2 and UQCISD(T) calculations, with 6-311G** basis sets, were performed for the titled reactions. The results show that the reactions have two product channels: NH2+ HNCO?NH3+NCO (1) ...
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Article
Ab initio study on the mechanism of rhodium-complexcatalyzed carbonylation of methanol to acetic acid
The whole catalytic cycle of the carbonylation of methanol to acetic acid catalyzed by Rh complex is theoretically studied. All structural geometries of reactant, intermediates, transition states and product a...
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Article
Theoretical investigation on regioselectivity of aromatic ketones in the addition with olefin catalyzed by RuH2(CO)(PPh3)3
Ab initio method is employed to study the structures of twelve aromatic ketones at HF/3-21G, HF/6-31G and HF/6-31G* levels, respectively. A theoretical analysis is also carried out to study the r...
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Article
Ab initio MO study of reaction mechanism for carbonyl migration of Co complex
Ab initio method under the effective core potential (ECP) approximation is employed to study the reaction mechanism of carbonyl migration of the cycle of olefin hydroformylation catalyzed by a ca...
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Article
Theoretical calculation of rate constants for the thermal isomerization from 1, 2-butadiene to 1, 3-butadiene
Ab initio electronic structure calculations at 6-31G** level were performed to determine the mechanism of the isomerization reaction from 1, 2-butadiene to 1, 3-butadiene. The MP2 method was used...
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Article
Theoretical investigation on mechanism of dissociation of furan
According to the calculated results for the dissociation mechanism of C4H4O+, we come to a conclusion as follows:
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Reaction (1)...
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