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Article
A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior
A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C6H16N)2[CoBr2.06Cl1.94] (1) were prepared at room temperature t...
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Article
Spectroscopic, Structural and Thermal Properties of Three New Metal Nitrates Templated by DABCO: (C6H14N2)[MII(H2O)6](NO3)4 with MII: Mn, Ni and Zn
Three new metal nitrates templated by 1,4-diazabicyclo[2.2.2]octane (DABCO) were successfully synthesized by slow evaporation method from aqueous solutions. Single crystals were characterized by X-ray diffract...
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Article
Phase transition from disordered high-temperature to twinned low-temperature structure of tris(ethylenediamine)zinc(II) selenate
The tris(ethylenediamine)zinc(II) selenate, [Zn(C2H8N2)3](SeO4), has been successfully synthesized and crystallographically characterized. It crystallizes at 293 K in the non-centrosymmetric space group P31c of t...
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Article
Two organically templated metal sulfate/selenate: IR spectroscopy, crystal structure, and thermal behaviour
Two organically templated transition metal sulfate/selenate compounds with following formula (C6H14N2)[Co(H2O)6](S0.83Se0.17O4)2 (1) and (C4H12N2)[Cu(H2O)4(S0.39Se0.61O4)2]·2H2O (2) have been synthesized and crys...
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Article
Effect of the partial substitution of sulfur by selenium on the atomic arrangement in sulfate- and selenate-based compounds
Two new co-based hybrid materials, (C4H12N2)[Co(H2O)6](S0.689Se0.311O4)2 (1) and (C4H12N2)[Co(H2O)6](S0.80Se0.20O4)2 (2), have been synthesized by slow evaporation method at room temperature and crystallographica...
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Article
Thermal decomposition and biological activity of two supramolecular hybrid nitrates templated by piperazine
The combination between piperazine, nitrate anions and nickel/zinc metals provided two new hybrid compounds with the general formula (C4H12N2)2[MII(H2O)6](NO3)6 [MII: Ni (1) and Zn (2)]. Their characterization is...
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Article
A new nickel selenate templated by piperazine: chemical preparation, crystal structure, thermal decomposition, and magnetic properties
Single crystals of (C4H12N2)[Ni(H2O)6](SeO4)2 were synthesized by the slow evaporation method from an aqueous solution of piperazine hexahydrate, nickel(II) carbonate, and selenic acid. This hybrid compound cryst...
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Article
A new organically templated magnesium sulfate: structure, spectroscopic analysis, and thermal behaviour
A new magnesium sulfate templated by 2-methylpiperazine, (C5H14N2)[Mg(H2O)6](SO4)2, was prepared by the slow evaporation method. The obtained crystals were investigated by the Raman and FTIR spectroscopy and crys...
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Article
Synthesis, Crystal Structure and Characterization of a New Dabcodiium Hexaaquacobalt(II) Bis(Selenate), (C6H14N2)[Co(H2O)6](SeO4)2
The new hybrid material, cobalt selenate templated by 1,4-diazabicyclo[2.2.2]octane (abbreviated dabco), has been synthesised by the slow evaporation method at room temperature. Its crystal structure was inves...
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Article
Crystal Structure, Phase Transition and Thermal Behaviour of Dabcodiium hexaaquacopper(II) bis(selenate/sulfate), (C6H14N2)[Cu(H2O)6](S0.66Se0.34O4)2
A new organically templated metal sulfate/selenate has been synthesized by the slow evaporation method and crystallographically characterized. At room temperature, the dabcodiium hexaaquacopper(II) bis(selenat...
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Article
A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition
The crystal structure of manganese sulfate templated by 1,4-diaza-bicyclo[2.2.2]octane (abbreviated dabco), (C6H14N2)[Mn(H2O)6](SO4)2, was investigated using single crystal X-ray diffraction data. It crystallises...
