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Article
Lattice Dynamics and Electronic Properties of a BaGa2GeS6 Nonlinear Crystal: Raman Scattering, IR Reflection, and ab initio Calculations
We have measured the polarized Raman scattering and IR reflection spectra of a BaGa2GeS6 crystal, the Ga and Ge atoms of which are disordered, randomly occupying crystallographic positions of the same kind. The I...
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Article
Dysprosium thiogallate laser: source of mid-infrared radiation at 2.4, 4.3, and 5.4 µm
Various Dy:PbGa2S4 laser-active material energy transitions originating from the 6H9/2 + 6F11/2 or 6H11/2 energy level were investigated, and the mid-infrared radiation generation has been demonstrated. The Dy:Pb...
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Article
Luminescence of lead thiogallate single crystals doped with cerium ions
The luminescence of single crystals of lead thiogallate PbGa2S4: Ce3+ has been studied. The observed nonmonotonic temperature dependence of the integrated luminescence intensity of PbGa2S4: Ce3+ has been explaine...
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Article
Electron paramagnetic resonance of Ce3+ ions in lead thiogallate single crystals
The results of electron paramagnetic resonance (EPR) studies of Ce3+ impurity ions in single crystals of lead thiogallate PbGa2S4 have been reported. The Ce3+ ions substitute for Pb2+ ions in the crystal lattice ...
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Article
Electron paramagnetic resonance of Dy3+ ions in lead thiogallate single crystals
The results of electron paramagnetic resonance (EPR) studies of Dy3+ ions in lead thiogallate PbGa2S4 single crystals have been presented. It has been shown that the ground state of these ions corresponds to the ...
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Article
Growth and X-ray Diffraction Study of Tl4HgI6 Crystals
Single crystals of red and black Tl4HgI6 phases are grown, and their structures are determined by x-ray diffraction. All of the crystals are found to have the noncentrosymmetric space groupP4nc. The crystals cont...
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Article
Preparation and Structure of AgGa1 – x In x Se2 Single Crystals
AgGa1 – x In x Se2 single crystals grown by the Bridgman–Stockbarger method, using presynthesized charges with x = 0.27, 0.335, and 0.375 are studied by x-ray diffraction (phase ...
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Article
CO2-Laser Second Harmonic Generation in HgGa2S4
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Article
High-frequency EPR of Cr2+ ions in CdGa2S4
High-frequency broad-band (65–240 GHz) EPR is used to study impurity centers of bivalent chromium in a CdGa2S4 crystal. It is found that the EPR spectra correspond to tetragonal symmetry. The spin Hamiltonian H =...
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Article
Parametric Frequency Converters Based on New Nonlinear Crystals
Results of investigations into the physical properties of a number of new nonlinear crystals are presented. The parameters of frequency converters manufactured on their basis are compared, and second-harmonic ...