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Chapter
Photodegradation of Organic Photochromes
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Article
A solid-state (CP-MAS)13C nuclear magnetic resonance study of selected photo(thermo)chromic spiro-(indolinonaphthoxazine)s
Liquid and solid-state13C NMR data are reported for three photo(thermo)chromic spiro-(indolinonaphthoxazine)s,1–3. The isotropic13C chemical shifts are almost identical in the solid state and in solution. Therefo...
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Chapter and Conference Paper
Studies on Some Trifluoromethyl Nitroxide Radicals by EPR Spectroscopy
The hyperfine splitting by 17O in (CF3)2N170• is 23.6 G which is appreciably larger than the 19.4 G reported for [(CH3)3C] 2N170• and indicates that the former radical has a relatively high spin density on oxygen...
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Chapter and Conference Paper
Quantum Mechanical Tunneling in Free Radical Reactions
Examples of free radical reactions are described for which convincing evidence for quantum-mechanical tunneling has been reported. They include: H-atom abstraction reactions by thermalized methyl radicals and ...