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Article
Biocatalytic, enantioenriched primary amination of tertiary C–H bonds
Intermolecular functionalization of tertiary C–H bonds to construct fully substituted stereogenic carbon centres represents a formidable challenge: without the assistance of directing groups, state-of-the-art ...
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Article
Versatile and robust C–C activation by chelation-assisted manganese catalysis
C–H activation has been recognized as an increasingly viable tool in molecular sciences, but organometallic C–C activation is scarce, and limited to precious and toxic metal catalysts. Herein, we disclose vers...