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Article
Binding of Bile Salts to an Amphiphilic Polysulfonate Modified with Cholesterol Moieties
A hydrophobically modified polysulfonate bearing a small mole percent (5 mol %) of cholesteryl moieties forms an intermolecularly bridged flower micelle in water, arising from intermolecular associations of th...
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Article
pH-Responsive Micellization of Amine-Containing Cationic Diblock Copolymers Prepared by Reversible Addition-Fragmentation Chain Transfer (RAFT) Radical Polymerization
A series of poly([3-(methacryloylamino)propyl]trimethylammonium chloride)-block-poly(2-(diethylamino)ethyl methacrylate) (pMAPTACm–DEAEMAn) of different block lengths were prepared by controlled radical polymeriz...
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Article
Aggregation Number of Cholesterol Moieties in Hydrophobic Microdomains Formed by Self-Association of a Cholesterol-Bearing Polyelectrolyte in Water
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Article
Synthesis and Characterization of Self-Associative Perfluoroalkyl-End-Capped Polystyrene
Polystyrene bearing a perfluoroalkyl group at one polymer chain end was synthesized by a “living” radical polymerization of styrene in the presence of 4-perfluoro(n-tetradecanoylamino)-2,2,6,6-tetramethylpiperidi...
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Article
Optical Anisotropy of Photo-Crosslinkable Polymer Film and Photoalignment Control of Nematic Liquid Crystals Using Nonpolarized Ultraviolet Irradiation
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Article
Linearly Polarized Ultraviolet Photoreaction of Poly[6-(4′-cinnamoylbiphenyl-4-yloxy)hexyl methacrylate] and Alignment Behavior of Liquid Crystals on the Resultant Photoreacted Films
Linearly polarized (LP)-ultraviolet (UV) photoreaction of side-chain liquid crystalline polymer of poly[6-(4′-cinnamoylbiphenyl-4-yloxy)hexyl methacrylate] (SLCP 1) and low-molecular-weight (LMW)-LC alignment beh...
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Article
Radical Polymerization of Monovinyl Sebacate and Poly(vinyl alcohol) from Its Polymer
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Article
Preparation of Highly Syndiotactic Poly(vinyl alcohol) by Fractionation
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Article
Poly(vinyl alcohol) with High Diad-Syndiotacticity and High Melting Point
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Article
Synthesis and Photoreaction of Poly[6-(4′-cinnamoylbiphenyloxy)-hexylmethacrylate-co-methylmethacrylate]
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Article
Solvent Effects on the Radical Polymerization of Vinyl Pivalate
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Article
Estimation of Sequence Distribution in Poly(vinyl acetate)
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Article
Biodegradation of Poly(vinyl alcohol) with High Isotacticity
A bacterium having biodegrading activity with poly(vinyl alcohol) (PVA) was isolated from an activated sludge sample of a textile dyeing factory which deals with PVA. The bacterium was identified as a strain of P...
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Article
Initiation Step of Radical Polymerization of Styrene in Various Non-Aromatic Solvents
Rates of initiation of radical polymerizations (Ri) of styrene by several initiators in non-aromatic solvents were determined and compared with those in benzene. It is considered that by forming π-complex with a ...
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Article
Tacticities of Copoly(vinyl ester)s Obtained by Radical Polymerization
Tacticity simulations of poly(vinyl acetate-co-vinyl propionate) [poly(VAc-co-VPr)], poly(vinyl acetate-co-vinyl decanoate) [poly(VAc-co-VD)] and poly(vinyl acetate-co-vinyl pivalate) [poly(VAc-co-VP)] were tried...
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Article
Synthesis of High-Molecular Weight Poly(vinyl alcohol) of Various Tactic Contents through Photo-Emulsion Copolymerization of Vinyl Acetate and Vinyl Pivalate
Photo-emulsion copolymerizations of vinyl acetate (VAc) and vinyl pivalate (VP) were carried out without initiator at 0°C, and copolymers giving high molecular weight poly(vinyl alcohol) (PVA) with various tac...
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Article
Saponification of High Molecular Weight Poly(vinyl pivalate)
The saponification of high molecular weight poly(vinyl pivalate) (PVP) was examined in several solvents, and PVA of Pn=18000 and 99%DS (degree of saponification) were obtained by saponification in the absence of ...
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Article
Dynamic Mechanical Behaviors of Poly(vinyl alcohol) Film with High Syndiotacticity
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Article
High Molecular Weight Poly(vinyl alcohol) through Photo-Emulsion Polymerizations of Vinyl Acetate
A mixture of vinyl acetate, water and polyoxyethylene nonyl phenyl ether sodium sulfate (LWZ; Kao Co.) was irradiated with a high pressure mercury lamp in the absence of initiator at 0°C and high molecular wei...
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Article
Preparation and Saponification of High Molecular Weight Poly(vinyl pivalate)