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Chapter
Complex systems in the gas phase
Experimental and theoretical investigations of ultrafast processes in molecules or clusters can lead to a detailed understanding of the dynamical processes involved. Their control by tailored laser pulses can ...
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Chapter and Conference Paper
Time-Resolved Photoelectron Spectroscopy of Excited State Intramolecular Proton Transfer Dynamics
Time-resolved photoelectron spectroscopy of excited state intramolecular proton transfer is presented for the first time. In o-hydroxybenzaldehyde, it occurs within 100 fs on an almost barrierless potential. T...
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Chapter and Conference Paper
Untangling π-π*/n-π* Orbital Interactions via Ultrafast Time-Resolved Photoelectron Spectroscopy
The ultrafast photochemical dynamics of π-π*/n-π* orbital interactions are determined using time-resolved photoelectron spectroscopy. We compare the spectra of several linear α,β-enones and 1,3-butadiene. We f...
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Chapter and Conference Paper
The UV Band System of the Allyl Radical, Studied by Time-Resolved Photoelectron Spectroscopy
The nonradiative decay of the UV band system of the allyl radical is studied by picosecond time-resolved photoelectron spectroscopy. Lifetimes are determined for all vibronic bands previously assigned in ns-MP...