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Article
The Interrelation between Iron Valence and Oxygen Vacancies in Substituted Orthoferrite La0.67Sr0.33FeO3 – γ during Heat Treatment
In this paper, we studied substituted lanthanum orthoferrite La0.67Sr0.33FeO3 – γ by Mössbauer spectroscopy using X-ray diffraction data. A series of vacuum annealings was performed in the temperature range of ta...
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Article
Magnetic Hyperfine Interactions of 57Fe Probe Atoms in the CaCuxMn7 – xO12 (0 ≤ x ≤ 1) Manganites
Magnetic and Mössbauer measurements are performed on the nuclei of 57Fe probe atoms in the structure of the substituted CaCuxMn6.96 – x57Fe0.04O12 (0 ≤ x ≤ 1) manganites in the magnetic-ordering temperature range...
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Article
Probe Mössbauer Diagnostics of Charge Ordering in Manganites CaCuxMn7–xO12 (0 ≤ x ≤ 1)
We present the results of our 57Fe probe Mössbauer study in manganites CaCuxMn6.96–x57Fe0.04O12 (0 ≤ x ≤ 1). We have established that for compositions 0 ≤ x ≤ 0.15 near the structural R\(\bar {3}\) ↔ Im$$\bar {3}...
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Article
Hyperfine Magnetic Fields at the Nuclei of 57Fe in the Intermetallic System Zr1 –xScxFe2
Mössbauer studies of the anisotropy of hyperfine interactions (HFIs) of the 57Fe nuclei in the quasi-binary intermetallic system Zr1 –xScxFe2 (0 ≤ x ≤ 1) with the structure of the cubic Laves phase of the C15 typ...
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Article
Temperature investigations of the spatial spin-modulated structure of multiferroic BiFeO3 by means of Mössbauer spectroscopy
The results from 57Fe Mössbauer spectroscopic studies of multiferroic BiFeO3 in a range of tem-peratures including that of the magnetic phase transition are presented. The Mössbauer spectra are processed and anal...
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Article
Diagnostics of a spatial spin-modulated structure using nuclear magnetic resonance and Mössbauer spectroscopy
Methods of the diagnostics of the spatial spin-modulated structure of the cycloidal type in multiferroics based on nuclear magnetic resonance and Mössbauer spectroscopy have been considered. It has been establ...
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Article
Mössbauer and magnetic studies of nanocomposites containing iron oxides and humic acids
Nanocomposites containing iron oxides and humic acids were studied by Mössbauer and magnetic measurements. The concentrations of humic acids as the precursor in nanocomposites were varied. Mössbauer investigat...
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Article
Hyperfine magnetic fields at the nuclei of probe 119Sn atoms and exchange interactions in the CaCu3Mn3.96Sn0.04O12 manganite
We have investigated the hyperfine magnetic interactions between the nuclei of probe 119Sn atoms in the CaCu3Mn3.96Sn0.04O12 double manganite by Mössbauer spectroscopy using magnetic measurements. A consistent de...
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Article
57Fe and 119Sn probe Mössbauer spectroscopy investigation of perovskite-type double manganite family CaCu x Mn7−x O12 (x = 0, 0.15, 3)
CaCu x Mn7−x O12 (x = 0, 0.15, 3) manganites were studied by 57Fe and 119Sn probe Mössbauer spectroscopy. It was established that the 57Fe and 119Sn probe...
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Article
Structure of the local environment and hyperfine interactions of 57Fe probe atoms in DyNiO3 nickelate
The local structure of DyNiO3 nickelate at both sides of the insulator (T < T im) ↔ metal (T > T im) phase transition was studied by probe 57Fe Mössbauer spectrosco...
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Article
Electronic state of 57Fe probe atoms in perovskite-type Ni(III) and Cu(III) oxides
A comparative study of the electronic state of 57Fe probe atoms in nickelates and cuprates LaM 0.99 57Fe0.01O3 and LaSrM 0.99 ...
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Article
Electronic state of the 57Fe probe atoms in perovskites LaMO3 (M = Ni, Cu)
Mössbauer spectroscopy has been applied for comparative study of the electronic state of probe iron atoms in perovskite-like nikelate LaNi0.99 57Fe0.01O3 and cuprate LaCu0.99 ...
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Article
Magnetic hyperfine interactions of 119Sn probe atoms in the binary perovskite CaCu3Mn4O12
The manganite CaCu3Mn4O12 doped by 119Sn atoms (about 1 at % with respect to Mn atoms) is studied by Mössbauer spectroscopy. The introduction of diamagnetic tin atoms is found not to affect the structure of the m...
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Article
Mössbauer study of layered iron hydroxysulfides: Tochilinite and valleriite
Natural and synthetic layered iron hydroxysulfides: tochilinite and valleriite, have been investigated by Mössbauer spectroscopy. Tochilinite, magnetite, troilite, and pyrite phases were found in the products ...
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Article
119Sn and 57Fe Mössbauer study of the local structure of perovskite-type ferrites CaFe2 − x N x O5 (N = Sc, Al) and manganite CaMn7O12
Anion-deficient substituted ferrites Ca2Fe2 − x N x O5 (N = Sc3+, Al3+) and mixed manganite CaMn7O12 hav...
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Article
Mössbauer investigations of the CaMn7O12 double manganite with the nuclei of 57Fe probe atoms
The CaMn7O12 double perovskite-like manganite is studied using Mössbauer spectroscopy with 57Fe impurity atoms. The hyperfine parameters of the Mössbauer spectra are found to reflect the specific local structure ...
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Chapter and Conference Paper
Investigations of sulfide minerals with layered structure by Mössbauer spectroscopy methods
Samples obtained as a result of the tochilinite synthesis process were investigated by 57Fe Mössbauer spectroscopy. Tochilinite, magnetite and troilite were obtained in investigated samples. The dependences of ph...
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Article
Mössbauer investigations of natural and synthetic tochilinite and valleriite
Samples of natural and synthetic tochilinites and valleriites were investigated by Mössbauer spectroscopy. Synthesis of tochilinite was carried out at different temperatures and Fe/Mg ratio in the initial mixt...
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Article
Investigations of sulfide minerals with layered structure by Mössbauer spectroscopy methods
Samples obtained as a result of the tochilinite synthesis process were investigated by 57Fe Mössbauer spectroscopy. Tochilinite, magnetite and troilite were obtained in investigated samples. The dependences of ph...