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Article
Interaction of lipid-transport proteins from Nigella sativa seeds with lipid membranes
Three pure lipid-transport proteins (LTPs) were isolated from Nigella sativa seeds. The effects of the three LTPs on release of ANTS probe from the inner volume were studied using fluorescence in liposomes of ...
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Article
Membrane-active properties and antiradical activity of gossypol and its derivatives
A novel asymmetric gossypol derivative was synthesized. The antioxidant activity of gossypol and certain of its derivatives at the aldehyde groups and the interaction of these compounds with model membranes we...
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Article
Clathrates of dianilinegossypol with lower acetate ester homologues: Structure, isomorphism, and morphotropic transitions
The structure of dianilinegossypol clathrates is shown to be sensitive to size of the ester molecule included. The change in the guest component from methyl acetate to amyl acetate is accompanied by two morpho...
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Article
Ionophoric and Complexant Properties of Lagochilin Derivatives
The ionophoric and complexant properties of synthetic derivatives of lagochilin, 3,18-O-isopropylidenelagochilin and 3,18-O-ethylidenelagochilin, were studied by BLM methods, conductometry, and IR spectroscopy...
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Article
Polymorphism of dianilinegossypol
Polymorphs of dianilinegossypol are obtained by selecting the precipitation medium and the crystallization temperature. Four dianilinegossypol polymorphs are found. Two solvate forms and three polymorphic modi...
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Article
Synthesis, Structure, and Membrane Activity of New Glycyrrhetic Acid Derivatives
Derivatives of 3-O-acetyl-18-βH-glycyrrhetic acid were synthesized. Their structures and membrane activities were studied.
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Article
Molecular and crystal structure of 4′-cyanobenzo-15-crown-5
The crystal structure of 4′-cyanobenzo-15-crown-5 is determined by X-ray diffraction. The crystallographic parameters of single crystals are as follows: a = 40.479(6) Å, b = 8.821(2) Å, c = 8.484(2) Å, β = 93.94(...
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Article
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Article
Membrane-active properties of crambin
A thionin-like protein with M. M. 5kDa has been isolated fromCrambe kotschyana seeds. It has been shown that crambin possesses, a low lytic action on erythrocytes but inhibits the Ca-ATPase of the sarcoplasmic re...
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Article
Polymorphism of Inclusion Complexes and Unsolvated Hosts. V. Crystal Structure of the α-Dimorph of the 1 : 2 Dianilinegossypol–DMSO Complex and a 1 : 1 : 1 Inclusion Complex Based on a Mixed Dianilinegossypol/1,4-Dioxane Host Matrix and 1,2-Dichloroethane Guest
Dianilinegossypol forms a 1 : 2 host-guest complex with DMSO:monoclinic, space group P21/n, a = 8.522(3), b = 18.034(4), c= 28.462(6) Å, β = 94.14(2)°, V = 4362Å3, Z = 4, D x = 1.26 g cm-3, T = 295 K.Final R valu...
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Article
Polymorphism of Inclusion Complexes and Unsolvated Hosts. II. Structure of the β-Dimorph of the Host-Guest Complex of Dianilinegossypol with Ethylacetate
Depending on crystallization conditions, dianilinegossypol and ethylacetate form low (ambient temperature, α-phase) and high temperature (t = 35°C, β-phase) clathrate modifications. The structure of the α-phas...
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Article
Inclusion complexes of the natural product gossypol. Recognition by gossypol of halogeno methanes. Structure of the dichloromethane complex of gossypol and single crystal conservation after decomposition
The structures of gossypol complexes are extremely sensitive to the halogenomethane present as the guest; e.g. changing the number of Cl atoms in chloromethane derivatives changes the structure of the gossypol...
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Article
Influence of thionin on the structure of a bilayer and on the intermembrane exchange of lipid material
It has been shown that in lipid dispersions thionin causes the formation of heterogeneous structures with the production of lipid-enriched “clusters” melting at elevated temperatures. This effect of thionin de...
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Article
An investigation of the membranotropic properties of the plant toxin thionin isolated fromPyrularia pubera
It has been shown by the ESR of spin probes that thionin initially interacts with with negatively charged membranes electrostatically and then passes into the membranes to a depth comparable with the length of...
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Article
Inclusion complexes of the natural product gossypol. Crystal structure of the 2:1 complex of gossypol withm-Xylene
The crystal structure of a 2: 1 inclusion complex of gossypol withm-xylene has been determined by X-ray structure analysis. The crystals of C30H30O8·0.5C8 H10 are triclinic, space groupPl−,a = 8.478(1),b = 14.087...
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Article
X-ray structural investigation of gossypol and its derivatives. X. Unusual inclusion compounds based on gossypol
More than 100 crystalline molecular complexes of gossypol with various organic molecules have been obtained and identified, and for 67 of them single crystals have been grown and their crystallographic paramet...
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Article
X-ray structural investigation of gossypol and its derivatives. VII. Molecular and crystal structure of dianilinegossypol
A complete x-ray structural investigation of the complex of dianilinegossypol with ethyl acetate has been made and it has been shown that in these crystals the dianilinegossypol gossypol has predominantly the ...
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Article
NMR spectroscopy of interaction of some organophosphorus insecticides with liposomes
The interaction of the organophosphorus insecticides GA-41, chlorophos [trichlorfon] and OKh-30 with liposomes from lecithin and a mixture of lecithin and cardiolipin has been studied by NMR spectroscopy on1H and
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Article
An investigation of the interaction of cobra venom cytotoxins with liposomes by the fluorescent-probe method
The interaction of cytotoxins Vc1, Vc5, and Vc6 of the venom of the Central Asian cobra with liposomes having a negative surface charge prepared from a mixture of phosphatidylcholine and palmitic acid (1:1, molar...
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Article
Molecular and crystal structure of luteidine
The crystal structure of luteidine has been deciphered by x-ray structural analysis; there are two molecules in the independent part of its elementary cell. These symmetrically independent molecules differ in ...