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Article
Indoles
Dinordeoxy-10-methylhomoeseroline and a number of its derivatives, substituted in the benzene ring and at the indole nitrogen atom, were obtained by condensation in neutral, aqueous alcoholic solutions of aryl...
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Article
Indoles
The ring-chain tautomerism of compounds with the eserine skeleton has been investigated by UV and PMR spectroscopy. It is shown that these compounds exist in neutral solution in the cyclic α-aminoindoline form. I...
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Article
Indoles
A new method is proposed for the synthesis of dinordeoxyeserolines and echibolines having alkyl substituents at the indoline nitrogen atoms. This method is based on the reaction of N α ...
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Article
Indoles
A new method for the synthesis of the tricyclic system of eserine on the basis of the reaction of arylhydrazines with γ-halogenocarbonyl compounds possessing an α-methyl group in neutral media [2] has been pro...
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Article
Pyrazoles
The IR, UV, and NMR spectra of 3- and 5-pyrines, and of their thio, seleno, and imino analogs, are examined, and their pKa values measured. On the basis of the results, it is suggested that protonation in these s...