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Article
Open AccessIntegrating spin-dependent emission and dielectric switching in FeII catenated metal-organic frameworks
Mechanically interlocked molecules (MIMs) including famous catenanes show switchable physical properties and attract continuous research interest due to their potential application in molecular devices. The ad...
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Article
Systemic glucocorticoids link to long-term microvascular injury in COVID-19
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Article
Open AccessEnergy conversion and storage via photoinduced polarization change in non-ferroelectric molecular [CoGa] crystals
To alleviate the energy and environmental crisis, in the last decades, energy harvesting by utilizing optical control has emerged as a promising solution. Here we report a polar crystal that exhibits photoener...
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Article
Fluorescence emission modulation in cyanido-bridged Fe(II) spin crossover coordination polymers
Synergistic fluorescent spin crossover (SCO) bifunctional molecular materials have novel applications in the molecule-based magneto-optical switches. Herein, we report two novel three-dimensional (3D) Hofmann-...
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Article
Open AccessManipulating electron redistribution to achieve electronic pyroelectricity in molecular [FeCo] crystals
Pyroelectricity plays a crucial role in modern sensors and energy conversion devices. However, obtaining materials with large and nearly constant pyroelectric coefficients over a wide temperature range for pra...
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Article
Open AccessWater-oriented magnetic anisotropy transition
Water reorientation is essential in a wide range of chemical and biological processes. However, the effects of such reorientation through rotation around the metal–oxygen bond on the chemical and physical prop...
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Article
Open AccessMacroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex
Polarization change induced by directional electron transfer attracts considerable attention owing to its fast switching rate and potential light control. Here, we investigate electronic pyroelectricity in the...
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Article
Open AccessGiant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
Materials demonstrating unusual large positive and negative thermal expansion are fascinating for their potential applications as high-precision microscale actuators and thermal expansion compensators for norm...
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Article
Open AccessSuperior thermoelasticity and shape-memory nanopores in a porous supramolecular organic framework
Flexible porous materials generally switch their structures in response to guest removal or incorporation. However, the design of porous materials with empty shape-switchable pores remains a formidable challen...
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Article
Synthesis, structure, and magnetic properties of heterotrimetallic tetranuclear complexes
Two novel heterotrimetallic tetranuclear complexes [Cu(H2L)(CH3OH)]2Gd(DMF)Fe(CN)6·2H2O·DMF (1) and [Cu(H2L)(CH3OH)]2Tb(H2O)0.57(DMF)0.43Fe(CN)6·5.5H2O (2) are reported (H4L = N,N′-ethylenebis(3-hydroxysalicylide...
