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Article
Controlled radical polymerization with polyolefin macroinitiator: a convenient and versatile approach to polyolefin-based block and graft copolymers
This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared ...
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Article
Synthesis and hydrophilic property of polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA))
Polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)), which is a hydrophobic-hydrophilic graft copolymer, was synthesized by a combination of an atom transfer radical polymerization (ATRP) o...
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Article
New methodology for synthesizing polypropylene-graft-polystyrene (PP-g-PS) by coupling reaction with brominated polypropylene
Polypropylene-graft-polystyrene (PP-g-PS) was synthesized by the coupling reaction of brominated polypropylene produced by metallocene-catalyzed copolymerization of propylene with 11-bromo-1-undecene and polystyr...
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Article
Open AccessSynthetic method of polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid via reversible addition-fragmentation chain transfer (RAFT) polymerization with functionalized polyethylene
Polyethylene-poly(methylmethacrylate) (PE-PMMA) polymer hybrid was synthesized via RAFT polymerization of MMA with PE chain transfer agent (PE-CTA) for the first time. The structure of PE-CTA produced by seque...