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Article
Detection of lanthanides and actinides in solutions based on laser-induced luminescence and chemiluminescence
This work is devoted to applications of the time-resolved laser- induced luminescence spectroscopy and time-resolved laser-induced chemiluminescence spectroscopy for detection of lanthanides and actinides. The...
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Article
Initiation of luminol chemiluminescence by two-quantum excitation of U(IV) in aqueous solution
Results of experiments on initiation of luminol chemiluminescence by multiquantum excitation of U(IV) in aqueous solution by dye laser radiation in the visible range are reported.
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Article
Composition and stability constants of Np(V) fluoride complexes in chloride-fluoride melts
The absorption spectra of the NpO 2 + ion in the region of the 3 H 5← 3 H ...
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Article
Formation-decomposition equilibrium of the NpO 2 + ·UO 2 2+ complex in chloride melts
The absorption spectra of the NpO 2 + (5f 2) ion were examined in the region of the 3H 5 ← 3 H
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Article
NpO 2 + -UO 2 2+ cation-cation interaction in NaCl-KCl-CsCl and LiCl-KCl-CsCl eutectic melts
Absorption spectra of the NpO 2 + ion in UO 2 2+ -containing NaCl-KCl-CsCl (0.300:0.245:0.455) and LiCl-KCl...
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Article
First Observation of the Cation-Cation Interaction of Actinides in Melts: NpO2 +-UO2 2+ System
Study of the absorption spectra of the NpO 2 + ion in a CsCl melt containing 2 M UO 2 2+ , as well as in K2
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Article
Absorption Spectra of Cs2NaNdBr6 Crystal
The electronic and IR absorption spectra of the Cs2NaNdBr6 crystal were measured for the first time. By vibronic pattern analysis were localized 32 electronic transitions in the absorption spectra of the octahedr...
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Article
Absorption Spectra of the Octahedral Complex AmBr63- in the Cs2NaLuBr6 Crystal
Absorption spectra of the Cs2NaLuBr6:Am3+ (5 mol % of 243Am) were studied in the 450-2500 nm range at temperatures from 300 to 15 K. The spectra exhibited transitions from the ground level 7 F 0 of the Am3+ (f 6)...
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Article
Luminescence Spectra of Am3+ in Cs2NaLuBr6:Am3+ Bromoelpasolite
Luminescence spectra of the cubic crystal of Cs2NaLuBr6:Am3+ (2.5 mol % 243Am) were studied in the region of the (2 G 2, 5 D 2) → 7 F 0 (460-490 nm) and 5 L 6 → 7 F 0 (510-540 nm) transitions in the range from ro...
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Article
Manifestation of the Jahn-Teller effect in vibrational spectra of the MnF3 molecule
The experimental data on the structure and vibrational spectrum of the MnF3 molecule are analyzed. The vibrational modes are calculated and the vibrational spectrum of MnF3 is interpreted. A model of the electron...