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Article
Inertial Thermonuclear Fusion Using Explosive Magnetic Generators
There are two known directions of work on the implementation of inertial thermonuclear fusion using Z-pinches. In the first, to achieve thermonuclear ignition, it is proposed to compress the target by indirect...
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Article
Wide-aperture plasma-electrode pockels cell
The results of experimental investigations of wide-aperture (100 × 100 mm) plasma-electrode Pockels are presented. Time characteristics, contrast, transmission factor, and optical uniformity of the cell are me...
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Article
Kinetics of acid-assisted hydrolysis of pentachlorophenol in aqueous media
The rate of acid catalyzed hydrolysis of pentachlorophenol (PCP) can be described by the general equation-d[PCP]/dt = k exp[PCP]. The experimental pseudo-first order rate constant generall...
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Chapter and Conference Paper
Optical biopsy system for breast cancer diagnostics
An optical biopsy system for early breast cancer diagnostics is reported. Its specific features and calibration and data preprocessing method are described.
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Article
Stimulated Brillouin scattering of CO2 radiation in compressed xenon
Stimulated Brillouin scattering (STBS) and phase conjugation of CO2 laser radiation have been demonstrated experimentally for the first time in compressed xenon (59 atm at 21°C) located inside the low-Q cavity of...
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Article
Electrochemical reductive dehalogenation of chlorobenzenes
Electrochemical dechlorination of 1,2,3,5-tetrachlorobenzene in methanol and chlorobenzene in dimethylsulfoxide with tetraalkylammonium salts as supporting electrolytes was carried out. The extent of dechlorin...
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Chapter and Conference Paper
AML in the Elderly
Although the results of AML treatment have been considerably improved during the last years, it is almost entirely concerned the patients less than 60 years old. The age of the patient still remains one of the...
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Article
Syntheses of vitamins E and K1 catalyzed by heteropoly acids
Heteropoly acids H3PW12O40 and H4SiW12O40 have been found to be efficient catalysts for condensation of isophytol with 2, 3, 5-trimethylhydroquinone and 1-acetoxy-4-hydroxy-2-methyl-naphthalene in the syntheses o...
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Article
Synthesis and properties of phosphorus-tungsten heteropolyacid H6P2W21O71
An electromembrane method has been proposed for the synthesis of H6P2W21O71, its resistance to heat in the solid state has been studied, and the Hammett acidity functions of concentrated aqueous solutions measure...
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Article
Alkylation of p-substituted phenols by heteropoly acids
Liquid-phase alkylation of p-tert-butylphenol (TBP) and p-cresol by olefins and benzyl chloride in the presence of solid heteropoly acids (HPA) H3PW12O40 and 25% H3PW12O40/SiO2 at 100–150°C provides high yields o...
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Article
Transalkylation of phenols over heteropoly acids
Transalkylation of 2,6-di-tert-butyl-4-R-phenols over solid heteropoly acids (H3PW12O40, H4SiW12O40, H3PW12O40/SiO2, H4SiW12O40/SiO2) in the presence of toluene or o-xylene as acceptors of a tert-butyl group at 1...
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Article
Study of reactions in the phosphate-tungstate system: Electromembrane synthesis of the heteropoly acid H3PW12O40
We have studied the electromembrane method for obtaining H3PW12O40. using31P,183W and17O NMR, we have studied the conversions of isopoly-and heteropolytungstates over a broad pH range. Depending on the acidity of...
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Article
Methods of preparing the heteropolyacid H3PW12O40
Ionexchange and electrochemical methods of preparing the heteropolyacid H3PW12O40 are studied. Conditions are found for preparing H3PW12O40 in quantitative yield using electrodialysis without ether extraction.
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Article
Adsorption of the heteropolyacid H4SiW12O40 by porous substrates
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Silicotungstic heteropolyacid is sorbed by silica gels, activated charcoal, and γ-Al2O3 from water and from o...
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Article
Catalysis of the dealkylation of derivatives of 2,6-di-tert-butylphenol by heteropoly acids
The tungsten heteropoly acids in acetic acid are the most active in the dealkylation of 4-alkyl-2,6-di-tert-butylphenols. The reaction is first order with respect to the substrate and with respect to the HPA, ...
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Article
Rate of electrophilic addition of acetic acid to 1-hexene when catalyzed by heteropoly acids
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The catalytic activity of heteropoly acids (HPA) in the reaction for the electrophilic addition of AcOH to 1-...
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Article
Acidity function of concentrated solutions of 12-tungstophosphoric acid
The authors have measured the Hammett acidity functions H0 of concentrated solutions of H3PW12O40 in water, aqueous dioxane, and acetic acid. In these solvents the acidity of H3PW12O40 is higher than those of sul...
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Article
An investigation of the acid properties of heteropoly acids in acetone and acetic acid by the electrical conductivity method
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The authors have measured the electrical conductivity of heteropoly acids (HPA.) based on Mo(VI), W(VI), and ...
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Article
Use of the electrical conductivity method to investigate the acid properties of heteropoly acids in nonaqueous solutions
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The authors measure the electrical conductivities of heteropoly acids (HPA) of the compositions H3PMo12O40, H
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