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Article
Covalent and Supramolecular Conjugates of Calixarenes with Some Fluorescent Dyes of the Xanthene Series
This review presents the systems with derivatives of calix[n]arenes and the commonly available fluorescent dyes of the fluorene series, such as rhodamines B, 6G, 123 and the fluorone series, such as fluorescein a...
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Article
Reference Materials of Composition of Biologically Active Substances
To ensure the uniformity of measurements and metrological traceability of measurement results in state regulation of ensuring the uniformity of measurements, including in healthcare and pharmaceuticals, refere...
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Article
Development of a Parenteral Medicinal Formulation of the New Antifungal Semisynthetic Polyene Antibiotic Amphamide
The search for new antifungal agents with improved chemotherapeutic properties has produced the semisynthetic polyene macrolide amphotericin B derivative amphamide, which has a number of clear advantages over ...
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Article
Synthesis of Tetraazide Derivatives of p-tert-Butylcalix[4]arene Using Copper-Catalyzed Nucleophilic Aromatic Substitution
Aromatic azido derivatives of p-tert-butylcalix[4]arene have been obtained for the first time using copper-catalyzed nucleophilic aromatic substitution of azide anion for bromide in 5,11,17,23-tetrabromo- 25,26,2...
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Article
Effect of ionizing radiation on the extraction of Am(III) with p-tert-butylthiacalix[4]arene from alkaline carbonate solutions
The effect of γ-irradiation of tert-butylthiacalix[4]arene (TCA) solutions in m-nitrobenzotrifluoride (NBTF) and tetrachloroethylene (TCE) on the extraction of 241Am from alkaline carbonate solutions was studied....
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Article
Comparative analysis of the binding of thiacalix[4]arene-monocrown-ethers with monovalent metal salts using MALDI mass spectrometry
MALDI mass spectrometry is used for the first time for the rapid assessment of the binding of thiacalix[4]arene-monocrown-ethers with metal cations (Li, Na, K, Cs, Cu, Ag). The work is performed on examples of...
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Article
Extraction of cesium and americium with p-alkylcalix[8]arenes from alkaline solutions
Previously unknown isononylcalix[8]arene was synthesized from commercially available isononylphenol. The properties of the product (solubility, extraction ability, tendency to aggregation) were compared with t...
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Article
Synthesis and structure of lower rim-substituted alkynyl derivatives of thiacalix[4]arene
Lower-rim substituted bis- and tetrakis(alkynyloxy)thiacalix[4]arenes in cone and 1,3-alternate configurations were synthesized by the Mitsunobu reaction, and their structure was determined using homoand heteronu...
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Article
Effect of copper(I) on the conformation of the thiacalixarene platform in azide-alkyne cycloaddition
New lower-rim tetrasubstituted p-tert-butylthiacalix[4]arene derivatives bearing alkyl, propargyl, or triazole-containing substituents were synthesized. The structures of these compounds were determined by 1D and...
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Article
Synthesis and aggregation properties of thiacalix[4]arene tetra-N-acylamides
First 1,3-alternate p-tert-butylthiacalix[4]arenes containing N-acylamide fragments have been synthesized by reaction of thiacalix[4]arene carboxylic acid chlorides with 2-substituted 4,5-dihydro-1,3-oxazoles, an...
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Article
Thiacalix[4]arene-containing M2Ln2 complexes (M = MnII, CoII; Ln = EuIII, PrIII): synthesis, structure, and magnetic properties
Three new representatives of thiacalix[4]arene-containing tetranuclear 3d-4f metal complexes with the M2Ln2 fragment (M = MnII, CoII; Ln = EuIII, PrIII) were synthesized. Their molecular and crystal structures we...
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Article
Synthesis and fluorescent properties of thiacalix[4]arenes containing terpyridyl fragments at the lower rim
New thiacalix[4]arenes tetrasubstituted by terpyridyl fragments at the lower rims in the 1,3-alternate stereoisomeric form were synthesized. The molecules interact with EuIII and TbIII in the DMF solution to form...
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Article
Unusual amidation reaction of asparagine-containing glycopeptide antibiotics in the presence of (benzotriazole-1-yl)oxy-tris(pyrrolidino)phosphonium hexafluorophosphate (PyBOP)
The coupling reagent (benzotriazole-1-yl)oxy-tris(pyrrolidino)phosphonium hexafluorophosphate (PyBOP) is widely used for the synthesis of different peptides and their amides, particularly carboxamides of glyco...
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Article
Synthesis, structure, and properties of a new representative of the family of calix[4]arene-containing [MnII 2MnIII 2]-clusters
A new representative of calix[4]arene-containing tetranuclear manganese complexes of the [MnII 2MnIII 2] type was obtained. According to the data of magnetoochemical studies, the c...
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Article
Synthesis, structure, and properties of nitronyl nitroxyl tetraradical with calix[4]arene framework
A reaction of calix[4]arene tetraaldehyde with 2,3-bis(hydroxyamino)-2,3-dimethylbutane in DMF resulted in the corresponding 1,3-dihydroxyimidazolidine tetraadduct, whose oxidation gave a calix[4]arene (1,3-alter...
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Article
tert-Butylthiacalix[4]arene monolayers as a biomimetic model for the oxidation of antioxidants with cytochrome c
The possibility of designing a model of sensor to antioxidants based on thiacalix[4]arene monolayers with immobilized cytochrome c was shown. The molecular surface area S 0 of thiacalix[4]arene in...
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Article
Catalytic properties of supramolecular systems based on polyoxyethylated calixarenes and amines
The rate of carboxylic ester cleavage by amphiphilic low-molecular-weight and polymeric amines in the presence of polyoxyethylated calix[4]arenes with different degrees of oxyethylation is determined by the fo...
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Article
Erratum to: “Composite Materials on the Basis of Phenylenecarboxylate Framework MOF-5 and Calix[4]arenes with Various Structures”
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Article
Composite materials on the basis of phenylenecarboxylate framework MOF-5 and calix[4]arenes with various structures
A comparative study of the texture and adsorption characteristics of newly synthesized composite materials based on 1,4-benzenedicarboxylate metal-organic framework MOF-5 and calix[4]arenes with various struct...
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Article
1,3-Cyclohexadiene hydrogenation in the presence of a palladium-containing catalytic system based on an MOF-5/calixarene composite
A palladium-containing material based on the new metal-organic framework structure MOF-5/20% calix[4]arene have been synthesized and characterized by physical and chemical methods for the first time. The catal...