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Open AccessMechanistic insights into excited-state palladium catalysis for C–S bond formations and dehydrogenative sulfonylation of amines
Photocatalytic selective C(sp3)–H activation/cross-coupling reactions are appealing in organic synthesis. In this manuscript, we describe the development of photoexcited-state Pd-catalyzed dehydrogenative β-sulfo...
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Article
Open AccessModulating stereoselectivity in allylic C(sp3)-H bond arylations via nickel and photoredox catalysis
While significant progress has been made in develo** selective C-H bond cross-couplings in the field of radical chemistry, the site and stereoselectivity remain a long-standing challenge. Here, we present th...
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Article
Open AccessMechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer
Various methods that use a photocatalyst for electron transfer between an organic substrate and a transition metal catalyst have been established. While triplet sensitization of organic substrates via energy t...
