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    Book

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    Chapter

    Counting Statistics

    The net intensity of emitted characteristic X-radiation from an element in a matrix is related to the concentration of that element. Fig. 5.1 illustrates the theoretical correlation between the peak intensity R ...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Trace Analysis

    Since X-ray fluorescence spectrometry is essentially a method which counts atoms, the question naturally arises as to what is the minimum number of atoms which are required in order to give a measurable signal...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Physics of X-Rays

    The X-ray region is normally considered to be that part of the electromagnetic spectrum lying between 0.1-100 Å, being bounded by the γ-ray region to the short wavelength side and the vacuum ultra-violet regio...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Detection

    The basic problem of X-ray detection is that of converting the X-rays into a form of energy which can be measured and integrated over a finite period of time. There are numerous ways of doing this and each met...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Quantitative Analysis

    The preceding chapters have discussed the various random and systematic errors which can arise during an analysis either from the equipment or from the sample to be analysed and it is the purpose of this secti...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Dispersion

    The basic function of the spectrometer is to provide a means of isolating a selected wavelength from the polychromatic beam of characteristic radiation excited in the sample, in order that individual intensity...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Pulse Height Selection

    Pulse height selection affords a method of isolating a moderately narrow range of wavelengths from a spectrum by virtue of energy separation as opposed to wavelength separation as, for example, in crystal disp...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Matrix Effects

    The basis of quantitative X-ray fluorescence spectrometry is to follow the identification of a certain element in a mixture of elements (the matrix) with a measurement of the intensity of one of its characteri...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)

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    Chapter

    Sample Preparation

    Since X-ray spectrometry is essentially a comparative method of analysis, it is vital that all standards and unknowns be presented to the spectrometer in a reproducible and identical manner. Any method of samp...

    R. Jenkins, J. L. De Vries in Practical X-Ray Spectrometry (1970)