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Article
Electrochemical ion insertion from the atomic to the device scale
Electrochemical ion insertion involves coupled ion–electron transfer reactions, transport of guest species and redox of the host. The hosts are typically anisotropic solids with 2D conduction planes but can al...
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Article
Persistent and partially mobile oxygen vacancies in Li-rich layered oxides
Increasing the energy density of layered oxide battery electrodes is challenging as accessing high states of delithiation often triggers voltage degradation and oxygen release. Here we utilize transmission-bas...
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Article
Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides
Reversible high-voltage redox chemistry is an essential component of many electrochemical technologies, from (electro)catalysts to lithium-ion batteries. Oxygen-anion redox has garnered intense interest for su...