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Article
Modification of Properties of Composites Based on Ultra-High Molecular Weight Polyethylene by Creating Two-Layer Coatings with Low Molecular Weight Polyethylene on Filler Particles: Synthesis, Properties, and Application in 3D Printing by Selective Laser Sintering
Composites with a two-layer coating consisting of ultra-high molecular weight polyethylene and a lower molecular weight high-density polyethylene are synthesized by the sequential two-step polymerization of et...
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Article
Highly Filled Composite Materials Based on UHMWPE and a Mixture of Micron and Nanoscale Aluminum Particles
Highly filled (up to 90 vol %) UHMWPE composites with Al of controlled dispersed composition (micro-, nanoparticles, and their mixtures) were obtained by the polymerization filling method. The use of a mixture...
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Article
Electrical and Heat Conduction Properties of Polymerization-Filled Composites Based on Ultra-High-Molecular-Weight Polyethylene and Nano- and Micron-Sized Aluminum Particles
The electrical and heat conduction properties of polymerization-filled composites based on ultra-high-molecular-weight polyethylene and differently proportioned mixtures of aluminum micro- and nanoparticles co...
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Article
Composite Materials with Ultrahigh-Molecular-Weight Polyethylene and Boron Synthesized via Polymerization in situ
Composite materials made of ultrahigh-molecular-weight polyethylene (UHMWPE) and boron have been synthesized using polymerization filling (polymerization in situ), varying the boron content in a wide range fro...
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Article
Synthesis of isotactic polybutene-1 over titanium-magnesium catalysts with polydentate phosphine oxides as external electron donors
The polymerization of 1-butene over the TiCl4/MgCl2 (TMC) catalyst with the use of substituted phosphine oxides R n P(O)(CH2OR′)3 − n (R = alkyl, R′ = methyl or ...
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Article
Production of nanosized aluminum powders and their application as fillers for composite materials based on ultrahigh molecular weight polyethylene (UHMWPE)
A modified levitation-in-flow Gen-Miller technique is developed to produce nanodisperse aluminum particles 40–200 nm in size with a barrier coating of controlled thickness made of aluminum oxides and (oxy)nitr...
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Article
On the fracture of composites based on ultrahigh-molecular-weight polyethylene and fine aluminum particles
Mechanical characteristics of polymerization filled composite materials based on ultrahigh-molecular-weight polyethylene and fine aluminum particles are studied. The prepared composites preserve their ability ...
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Article
Polydentate phosphine oxides as external electron donors for titanium-magnesium catalysts for propylene polymerization
The possibility of using R n P(O)(CH2OR′)3—n (R = alkyl, R′ = methyl or acyl, n = 0–2) polydentate phosphine oxides as external electron donors for the t...
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Article
Effect of the zeolite support on the polymerization of propylene with immobilized ansa-zirconocene catalysts
Anchored aluminoxanes are synthesized by the reaction of aluminum alkyls AlMe3 and Al(i-Bu)3 with water contained in the intracrystalline cavities of synthetic and natural zeolites (NaY (Si: Al = 5), HZSM-5 (Si: ...
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Article
“Polydentate phosphine oxides as new electron-donor components of titanium-magnesium catalysts for the synthesis of isotactic poly(1-butene)”
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Article
Immobilized organometallic catalysts in the catalytic polymerization of olefins
Studies in the field of supported Ziegler-Natta catalysts employed for the polymerization of olefins that were begun by works performed under the guidance of Prof. Chirkov are reviewed in brief. The developmen...
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Article
Polydentate phosphine oxides as new electron-donor components of titanium-magnesium catalysts for the synthesis of isotactic poly(1-butene)
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Article
Olefin polymerization on immobilized zirconocene catalysts containing alkylaluminoxanes synthesized on the support surface
Ethylene and propylene polymerization on immobilized catalysts of composition MMT-H2O/AlR3/Zr-cene (MMT = montmorillonite) and on the corresponding homogeneous catalysts of composition Zr-cene-MAO (Zr-cene = rac-...
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Article
Organophosphorus complexones as catalysts for but-1-ene polymerization
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Article
Influence of the catalyst matrix structure of the supported Ziegler-Natta catalysts on the homo- and copolymerization of olefins
The vanadium catalytic complexes immobilized on the same support (aluminium hydroxide, AH) and distinguished by structure and composition have been compared for ethylene and propylene homo- and copolymerizatio...