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Article
Open AccessNickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes
The development of efficient and sustainable methods for the construction of carbon-carbon bonds with the simultaneous stereoselective generation of vicinal stereogenic centers is a longstanding goal in organi...
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Article
Gold unleashes the power of three
Gold in the +3 oxidation state is scarcely used in catalysis, because the oxidants employed to generate it can damage reactants. An oxidant-free route to gold(III) catalysts reveals their potential. See Article
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Asymmetric Transformations via C–C Bond Cleavage
Catalytic asymmetric transformations operating by carbon–carbon (C–C) bonds cleavages have emerged as intriguing strategies to access transient organometallic species from different reaction pathways. The reac...