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Article
Effect of Dinitrosyl Iron Complexes (NO Donors) on the Metabolic Processes in Human Fibroblasts
The results of the study of the effect of mononuclear dinitrosyl iron complexes (DNICs) with functional sulfur-containing ligands (NO donors) on the cell viability and metabolism of human lung fibroblasts are ...
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Article
Quantum chemical modeling of possible reactions of mononuclear iron nitrosyl complex [Fe(SC(NH2)2)2(NO)2]Cl•H2O in an aqueous solution
Possible reactions of the mononuclear iron nitrosyl complex [Fe(SC(NH2)2)2(NO)2]Сl•H2O in an aqueous solution were studied using quantum chemical modeling. The electronic structures of the possible intermediates ...
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Article
Effects of Nitrosyl Iron Complexes with Thiocarbamide and Its Aliphatic Derivatives on Activities of Ca2+-ATPase of Sarcoplasmic Reticulum and cGMP Phosphodiesterase
We studied the effects of water-soluble cationic dinitrosyl iron complexes with thiocarbamide and its aliphatic derivatives, new synthetic analogs of natural NO donors, active centers of nitrosyl [1Fe-2S]prote...
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Article
Molecular and crystal structure of a cationic dinitrosyl iron complex with 1,3-dimethylthiourea
A new dinitrosyl iron complex of the composition [Fe(SC(NHCH3)2)2(NO)2]Cl (I) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic fe...
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Article
Experimental and quantum chemical modeling of the influence of the pH of the medium on the NO-donor activity of the mononuclear nitrosyl iron complex [Fe(SC(NH2)2)2(NO)2]Сl•H2O
The electrochemical method and quantum chemical modeling were used to study the NO-donor activity of the mononuclear nitrosyl complex with the thiourea ligand and the influence of the pH of the medium on the r...
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Article
Synthesis and properties of polyvinylpyrrolidone films containing iron nitrosyl complexes as nitric oxide (NO) donors with antitumor and antiseptic activities
New homogeneous water-soluble polyvinylpyrrolidone composites containing iron sulfur nitrosyl complexes as nitric oxide donors with antitumor and antiseptic activities were synthesized. The morphology of the c...