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Article
Influence of nonlinear interactions on the development of instability in hydrodynamic wave systems
The problem of the development of shear instability in a three-layer medium simulating the flow of a stratified incompressible fluid is considered. The hydrodynamic equations are solved by expanding the Hamilt...
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Article
Synthesis of Schiff bases from 3-amino-3-arylpropionic acid esters in aqueous medium
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Article
Biologically active cyclic polypeptides with fragments of β-amino acid derivatives isolated from marine organisms (review)
Published data on the structure, stereochemistry, and biological activity of natural cyclic polypeptides containing fragments of β-amino acids are reviewed, and an attempt is made to relate the structure to th...
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Article
Stabilization of a linearly unstable wave participating in a three-wave resonant interaction
An analytical study of the influence of three-wave resonant interactions on the evolution of unstable wave disturbances is presented in the Kelvin-Helmholtz model. These results may be of interest in analyzing...
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Article
Resonant interaction of waves of continuous and discrete spectra in the simplest model of a stratified shear flow
The equations of dynamics of eddy—wave disturbances of two-dimensional stratified flows in an ideal incompressible fluid that are written in a Hamiltonian form are used to study the resonant interaction of wav...
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Article
Hamiltonian description of shear and gravity shear waves in an ideal incompressible fluid
Methods of studying the dynamics of wave disturbances in st;ratified shear flows of an ideal incompressible fluid are considered. The equations governing the motions of interest represent Hamilton equations an...
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Article
Three-wave resonant interaction involving unstable wave packets
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Article
Effect of Microwave Irradiation on the Direction and Stereochemistry of Rodionov and Michael Reactions
The reactions of 2-phenylpropanal with ethyl hydrogen malonate and benzylamine (or benzylammonium acetate) and of ethyl 4-phenyl-2-pentenoate with benzylamine take different pathways, depending on the conditions.
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Article
Hamiltonian description of motion in a perfect stratified fluid
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Article
The Use of Microwave Activation in the Chemistry of Heterocyclic Compounds. (Review)
Published data on the successful application of microwave activation in the chemistry of various heterocycles over the last two years are discussed.
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Article
Synthesis and stereochemistry of chiral 2-azetidinones and 2-azetidinethiones. 2.* Study of the chiroptical properties of some 2-azetidinones
Circular dichroism (CD) spectra were taken for 13 2-azetidinones with one, two, and three asymmetric sites. A possible correlation was found between the sign of the Cotton effect (CE) of the n-π* transition of...
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Article
Synthesis and stereochemistry of chiral azetidin-2-ones and azetidine-2-thiones. 3. Stereodirected construction of theβ-lactam fragment of the thienamycin molecule
It has been shown possible to introduce an α-hydroxyethyl group trans-stereospecifically into position 3′ of 4-methyl-1-(α-methyl-benzl)azetidin-2-one. The stereochemistry of the asymmetric centers C(3′), C(3), a...
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Article
Stereochemistry of electrophilic substitution in β-lactam systems (review)
The literature data on the synthesis of 3-monosubstituted and 3,3-disubstituted β-lactams on the basis of reactions of lithium derivatives of 2-azetidinones with electrophiles are systematized.
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Article
Stereochemistry of the methylation of the (11S,4S) and (11S,4R) diastereomers of 4-methyl-1-(α-methylbenzyl)azetidin-2-one
The methylation of the lithium derivatives of the (11S,4S) and (11S,4R) diastereomers of 4-methyl-1-(α-methylbenzyl)azetidin-2-one proceeds stereospecifically with the formation of only trans-(3S,4S)- and trans-(...
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Article
β-Lactams: Relationship of structure and stereochemistry to biological activity
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Article
Asymmetrical alkylation of 1-[(s)-α-phenylethyl]-azethidinone-2
The methylation of the lithium derivative of azethidinone-2 which has a chiral substituent at the nitrogen atom is asymmetrical and leads, with an optical yield of 35%, to diastereomeric 3-methylated azethidin...
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Article
Synthesis of benzo(aminomethyl)indoles
The benzene ring in indoles has been aminomethylated in high yield by reaction with methylolphthalimide followed by hydrazinolysis of the phthalimidomethyl derivatives. In the hydrazinolysis of one of the phth...
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Article
Asymmetric methylation of 1-[(S)-α-phenylethyl]-2-azetidinone
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Article
Synthesis of 1-(α-phenylethyl)azetidin-2-ones
Phase-transfer catalyzed cyclization of racemic and optically active N-substituted β-aminoacids has given racemic and optically active 2-azetidinones, the spatial structures of which have been established by N...
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Article
Preparation of opticaly active 3-(1-methyl-1-phenylpropyl)indole and investigation of its chiral-optical properties
Optically active 3-(1-methyl-1-phenylpropyl)indole was obtained by dehydrogenation of the resolved [by means of (L)-10-camphorsulfonic acid] 3-(1-methyl-1-phenylpropyl)indoline. The chiral-optical properties o...