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Article
Formation of 5-fluoro-3-(4-fluoro-1-hydroxyimino-4,4-dinitrobutyl)isoxazole from 1,7-difluoro-3-hydroxyimino-1,1,7,7-tetranitroheptan-4-one and hydroxylamine
1,7-Difluoro-3-hydroxyimino-1,1,7,7-tetranitroheptan-4-one reacts with hydroxylamine hydrochloride in MeOH in the presence of AcONa to give 5-fluoro-3-(4-fluoro-1-hydroxyimino-4,4-dinitrobutyl)isoxazole.
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Article
Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one
3-Acyl-5-nitroisoxazoles were synthesized by heating 5,5,5-trinitropentan-2-one with LiCl in DMF at 100 °C as well as by heating oximino derivatives of 5,5,5-trinitro-, 5-chloro-5,5-dinitropentan-2-one or 4,4,...
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Article
Theoretical discussion of cyclodimerization of nitrile N-oxides to furoxans
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Based on the data of quantum-chemical calculations the cyclodimerization of nitrile N-oxides is a two-step re...
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Article
Structure of one-electron oxidation products of oximes
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According to the calculations based on the CNDO/2 and PNDO, the radicals and cation-radicals of oximes retain...
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Article
Polarity, anisotropy of polarizability, and spatial structures of certain gem-dinitroalkanes
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Dipole moments and polarizability anisotropies have been measured for a series of methyl- and halogen-substit...
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Article
Synthesis and thermochemical properties of dialkylfuroxans
A number of dialkylfuroxans was synthesized and their thermochemical properties, namely the heats of combustion and the enthalpies of formation, were studied.