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Article
Humidity responsiveness of a poly(N-isopropylacrylamide) gel with a PEG/water mixed solvent
This manuscript presents the humidity responsiveness of a poly(N-isopropylacrylamide) (PNIPAAm) gel, which was capable of exhibiting volume changes. The strategy for inducing volume changes in the gel capitalized...
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Article
Structural changes of polystyrene particles in subcritical and supercritical water revealed by in situ small-angle neutron scattering
Marine ecosystem degradation due to microplastic pollution is a significant environmental problem, as acknowledged by Sustainable Development Goal 14. Decomposition of plastics using near critical or supercrit...
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Article
Antimicrobial surface processing of polymethyl methacrylate denture base resin using a novel silica-based coating technology
This study investigated the surface characteristics of denture base resin coatings prepared using a novel silica-based film containing hinokitiol and assessed the effect of this coating on Candida albicans adhesi...
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Article
Evaluation of the rheological and rupture properties of gelatin-based hydrogels blended with polymers to determine their drug diffusion behavior
In this study, the drug diffusion behavior and kinetics of gelatin hydrogels that were prepared with polymers were evaluated in terms of their rheological and rupture properties. The rheological and rupture pr...
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Article
Temperature-dependent relationship between the structure and mechanical strength of volatile organic compound-free latex films prepared from poly(butyl acrylate-co-methyl methacrylate) microspheres
Latex films that are formed by evaporating dispersions in the absence of volatile organic compounds (VOCs) typically suffer from poor mechanical strength compared to solution-cast latex films. In our previous ...
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Article
Examination of cross-calibration and concentration linearity with quantitative gallium-67 single-photon emission computed tomography: phantom experiment
We evaluated whether scattered radiation should be considered for cross-calibration and concentration linearity with quantitative gallium-67 (67Ga) single-photon emission computed tomography (SPECT). The scanned ...
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Article
Mechanism of heat-induced gelation for ovalbumin under acidic conditions and the effect of peptides
The mechanism of the heat-induced gelation of ovalbumin (OVA) under acidic conditions and the effect of amphiphilic peptide additives on gelation were investigated using dynamic light scattering (DLS) and smal...
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Article
Open AccessVersatile whole-organ/body staining and imaging based on electrolyte-gel properties of biological tissues
Whole-organ/body three-dimensional (3D) staining and imaging have been enduring challenges in histology. By dissecting the complex physicochemical environment of the staining system, we developed a highly opti...
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Article
Chiral crystal-like droplets displaying unidirectional rotational sliding
The self-assembly of organic molecules into supramolecular materials with structural ordering beyond the nanometre scale is challenging. Here, we report the spontaneous self-assembly of a chiral discotic triph...
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Article
Network structure evolution of a hexamethylenetetramine-cured phenolic resin
The network structure evolution of a hexamethylenetetramine (HMTA)-cured novolac-type phenolic resin over a curing temperature range of 135–155 °C was investigated using 1H-pulse nuclear magnetic resonance spectr...
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Article
Precision polymer network science with tetra-PEG gels—a decade history and future
Tetra-PEG gels, near-ideal polymer networks prepared by cross-end-coupling of A and B tetra-functional poly(ethylene glycol) (PEG) prepolymers having complementary end groups, were first fabricated in 2008. Co...
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Article
Open AccessAmoeba-like self-oscillating polymeric fluids with autonomous sol-gel transition
In the field of polymer science, many kinds of polymeric material systems that show a sol-gel transition have been created. However, most systems are unidirectional stimuli-responsive systems that require phys...
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Article
Fast-forming hydrogel with ultralow polymeric content as an artificial vitreous body
Degradation-induced swelling in implanted hydrogels can cause severe adverse reactions in surrounding tissues. Here, we report a new class of hydrogel with extremely low swelling pressure, and demonstrate its ...
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Article
Open AccessMultiblock copolymers exhibiting spatio-temporal structure with autonomous viscosity oscillation
Here we report an ABA triblock copolymer that can express microscopic autonomous formation and break-up of aggregates under constant condition to generate macroscopic viscoelastic self-oscillation of the solut...
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Article
Structural evolution of a catalyst ink for fuel cells during the drying process investigated by CV-SANS
Polymer electrode fuel cells are fabricated by drying a ‘catalyst ink’, that is, a mixture of carbon, ionomers, Pt and water, and it is of particular importance to elucidate the structural evolution of the cat...
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Article
Dynamic light scattering study of the curing mechanisms of novolac-type phenolic resins
The curing behavior of a novolac resin (NV) cured with hexamethylenetetramine (HMTA), as well as the influence of an excess amount of HMTA on the curing reaction, were investigated by dynamic light scattering ...
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Reference Work Entry In depth
Structures in CL/P Nanocomposites
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Article
Small-Angle Neutron Scattering Study on Aggregation of 1-Alkyl-3-methylimidazolium Based Ionic Liquids in Aqueous Solution
Aggregation structures of 1-alkyl-3-methylimidazolium based ionic liquids (ILs) in aqueous solution were investigated by small-angle neutron scattering (SANS) from the viewpoint of alkyl chain length, n, and anio...
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Article
Specific Solvation of Benzyl Methacrylate in 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)amide Ionic Liquid
It has been established that poly(benzyl methacrylate) in a room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([C2mIm+][TFSA–]), exhibits lower critical solution temper...
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Article
Mechanical properties of a polymer network of Tetra-PEG gel
The elastic properties of Tetra-polyethylene glycol (PEG) gel, a four-armed PEG network gel, were studied by simulating the deformation of elastic networks containing defects that are randomly introduced to th...